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Effects of source material on epitaxial growth of fluorescent SiC
Linköping University, Department of Physics, Chemistry and Biology, Semiconductor Materials. Linköping University, The Institute of Technology.
University of Erlangen-Nuremberg.
Linköping University, Department of Physics, Chemistry and Biology, Semiconductor Materials. Linköping University, The Institute of Technology.
Linköping University, Department of Physics, Chemistry and Biology, Semiconductor Materials. Linköping University, The Institute of Technology.
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2012 (English)In: Thin Solid Films, ISSN 0040-6090, E-ISSN 1879-2731, Vol. 522, 7-10 p.Article in journal (Refereed) Published
Abstract [en]

The growth of fluorescent SiC using Fast Sublimation Growth Process was demonstrated using different types of SiC source materials. These were prepared by (i) high-temperature hot pressing, (ii) chemical vapor deposition and (iii) physical vapor transport. The optimized growth rates of 50 μm/h, 170 μm/h and 200 μm/h were achieved using the three types of sources, respectively. The best results in respect to growth rates are obtained using higher density sources. Fluorescent SiC layers with mirror-like morphology, very good crystal quality and yellowish or warm white light photoluminescence at room temperature were grown using all three types of the source materials.

Place, publisher, year, edition, pages
Elsevier, 2012. Vol. 522, 7-10 p.
Keyword [en]
Sublimation growth; Fluorescence; Photoluminescence; Silicon carbide
National Category
Natural Sciences
URN: urn:nbn:se:liu:diva-73709DOI: 10.1016/j.tsf.2011.10.176ISI: 000310782000003OAI: diva2:476177
Available from: 2012-01-11 Created: 2012-01-11 Last updated: 2016-05-13
In thesis
1. Sublimation Growth of 3C-SiC: From Thick Layers to Bulk Material
Open this publication in new window or tab >>Sublimation Growth of 3C-SiC: From Thick Layers to Bulk Material
2016 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Silicon carbide (SiC) is a semiconductor material which holds high promises for various device applications. It can be obtained in different crystal structures called polytypes. The most common ones are hexagonal (6H- and 4H-SiC) and cubic (3C-SiC) silicon carbide. The 6H- and 4H-SiC single crystal substrates are commercially available, while technologies for the growth of 3C-SiC are still under development. The unique 3C-SiC properties like isotropy, narrower bandgap (2.4 eV)  compared to hexagonal polytypes (about 3 eV) and high electron mobility make it better over hexagonal counterparts for some semiconductor applications, for example, metal oxide semiconductor field effect transistors (MOSFETs). However, due to lack of high quality material, the full potential of 3C-SiC in device applications has not been revealed. In addition, it has properties suitable to explore new concepts in efficient photovoltaics or solar driven hydrogen generation by water splitting.

There is a need for 3C-SiC seeds to grow large 3C-SiC crystals by the widely used Physical Vapor Transport (PVT) technique. In case of hexagonal SiC polytypes such seeds were produced by the Lely method during which hexagonal SiC crystals spontaneously nucleate on the inner walls of a crucible. However, the formation of 3C-SiC using the Lely method is rarely observed. Therefore, the 3C-SiC has to be heteroepitaxially grown on silicon or hexagonal SiC substrates. Silicon is an inexpensive material with very high crystalline quality. However, due to almost 20% mismatch in lattice parameters and 8% difference in thermal expansion coefficient there is a high density of structural defects formed at the 3C-SiC/Si interface. In contrast, the 3C-SiC/hexagonal SiC material system does not encounter such problems, but there are other challenges like polytype stability or formation of structural defects called double positioning boundaries (DPBs).

This thesis work mainly focuses on the growth of 3C-SiC on hexagonal SiC substrates using sublimation epitaxy. The research covers the development of growth process for thick (~1 mm) 3C-SiC layers, advancement of the growth process to eliminate DPBs and growth of bulk material using thick 3C-SiC layers as seeds. The 3C-SiC was grown on off-oriented hexagonal SiC substrates. The surfaces of such substrates contain high density of steps. Therefore, they have mostly been used for the growth of homoepitaxial hexagonal layers or bulk crystals via step flow mechanism. However, as demonstrated in this thesis, under special conditions the 3C-SiC with high crystalline quality can also be grown on off-oriented hexagonal substrates. The stability window for the growth of hexagonal and cubic polytypes on nominally on-axis hexagonal SiC substrates is also explored. Moreover, it is demonstrated how the temperature profile inside the graphite crucible is influenced by the change in thermal insulation properties and how such change results in enhanced polytype stability during the growth of thick SiC layers. In addition, different sources for sublimation epitaxial growth of doped SiC layers were analyzed to gain further understanding of new parameter windows.

As a part of this thesis, a sublimation etching of 6H-, 4H- and 3C-SiC polytypes is presented using two different etching arrangements in vacuum (10-5 mbar) and Ar ambient. It is demonstrated that this technique can be used to remove residual scratches on the surface as well as to obtain various surface step structures which could be used for the growth of graphene nanostructures.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2016. 45 p.
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 1760
National Category
Physical Sciences
urn:nbn:se:liu:diva-127802 (URN)978-91-7685-778-6 (Print) (ISBN)
Public defence
2016-06-09, Planck, Fysikhuset, Campus Valla, Linköping, 10:15 (English)
Available from: 2016-05-13 Created: 2016-05-13 Last updated: 2016-05-13Bibliographically approved

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