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Spectral and in vitro antimicrobial properties of 2-oxo-4-phenyl-6-styryl-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid transition metal complexes
Sardar Patel Mahavidyalaya.
Institute of Science, Nagpur.
Chorghade Enterprises.
Linköping University, Department of Physics, Chemistry and Biology, Biosensors and Bioelectronics. Linköping University, The Institute of Technology.
2012 (English)In: Spectrochimica Acta Part A - Molecular and Biomolecular Spectroscopy, ISSN 1386-1425, E-ISSN 1873-3557, Vol. 93, 348-353 p.Article in journal (Refereed) Published
Abstract [en]

2-oxo-4-phenyl-6-styryl-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid (ADP) was complexed with acetates of Mn(II), Ni(II), Cu(II) and Zn(II). The structures of the ligand and its metal complexes were characterized by microanalysis, IR. NMR, UV-vis spectroscopy, magnetic susceptibility and TGA-DTA analyses. Octahedral and square planar geometries were suggested for the complexes in which the central metal ion coordinated with -O donors of ligand and acetate ions. Each ligand binds the metal using carboxylate oxygens. The ligand and complexes were evaluated for their antimicrobial activities against different species of pathogenic bacteria and fungi. The present novel pyrimidine containing complexes could constitute a new group of antibacterial and antifungal agents.

Place, publisher, year, edition, pages
Elsevier , 2012. Vol. 93, 348-353 p.
Keyword [en]
Pyrimidine transition metal complexes, Spectral, Octahedral, Square planar geometry, Anti-microbial activity
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-77852DOI: 10.1016/j.saa.2012.02.096ISI: 000303956500052OAI: oai:DiVA.org:liu-77852DiVA: diva2:529736
Note
Funding Agencies|UGC, New Delhi||Available from: 2012-05-31 Created: 2012-05-31 Last updated: 2017-12-07

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Tiwari, Ashutosh

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