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A comparison of Fourier vs. Newtonian thermal analyse and its influence on the inverse kinetic growth calculation
Department of Mechanical Engineering and Industrial Organisation / Component Technology, Jönköping University, Jönköping.
Department of Mechanical Engineering and Industrial Organisation / Component Technology, Jönköping University, Jönköping.
(English)Manuscript (preprint) (Other academic)
Abstract [en]

Thermal analysis of cooling curves is a metallurgical process control tool. Any phase transformations and their kinetics are reflected in the cooling rate. An interpretation of the cooling rate and temperatures is coupled to critical parameters, which are needed to assure correct quality of the melt and to give recommendations to modify the melt. This paper was inspired by the question, how well does a thermal ana lysis with one or two thermocouples and subsequent numerical analysis reflect the real phase transformations which occur?

Inverse kinetic analysis using Fourier Thermal Analysis and Newtonian Thermal Analysis has been investigated using simulated cooling curves. The present study uses a direct simulation including a kinetic model for simulation of a eutectic phase. In this case, since the solidification sequence is well defined the inverse kinetic analysis should recreate the relation between the growth rate and supercooling of the eutectic phase. The Newtonian Thermal Analysis is based on an interpretation of a single thermal point with respect to solidification and contains a series of assumptions which are not entirely undoubted physically.

Consequently the inverse kinetic analysis results in random quality growth parameters. The Fourier Thermal Analysis is based on interpretation of temperature differences between two thermal points with respect to solidification. The calculations conducted, in combination with the inverse kinetic analysis reveal a stable procedure. The decisive parameter determining the quality of inverse analysis is the distance between the thermal points analysed. Closely situated thermal points assure the best quality. The Fourier Thermal Analysis reflects the solidification most correctly.

Keyword [en]
Inverse model, thermal analyze, fraction solid, kinetic model
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-87057OAI: oai:DiVA.org:liu-87057DiVA: diva2:584559
Available from: 2013-01-09 Created: 2013-01-09 Last updated: 2013-01-09
In thesis
1. On microstructure formation and mechanical properties in grey cast iron
Open this publication in new window or tab >>On microstructure formation and mechanical properties in grey cast iron
2004 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

A major user of cast components is the automotive industry, where the functionality of the components is related to environmental demands. Internal combustion engines are constantly being improved to emit less pollution. A vital part in this development is to increase the material properties of engine components during their life cycle. In particular, cylinder heads, cylinder blocks and piston rings for diesel engine are produced in grey cast iron. Cast iron is expected to be in use far into the foreseeable future, due to favourable properties and low production costs. This work has been devoted to study microstructure formation, the tensile properties of cast iron and to some extent defect formation.

The microstructure develops during solidification and solid state transformations. An inverse thermal analysis method was developed to study the kinetics of the microstructure formation. The inverse thermal analysis used, the Fourier method, analyses the cooling curves of two thermocouples to study the solidification or transformation. To decrease experimental errors, simulations have been done and the cooling curves were analysed. The best results were obtained when the thermocouples were placed close to each other.

With the help of the thermal analysis a time dependent and fading nucleation law of the eutectic cells was found to fit the experimental results best. The experiments were made by multiple thermal analyses, and six different types of inoculants were investigated. The eutectic growth behaviour during solidification was evaluated with inverse thermal analysis, and it was found that commercial inoculants not only affect the eutectic nucleation but they also control the eutectic growth rate.

Models of densities and volume changes are an integral part of a microstructure simulation of cast irons. These models are important for the inverse thermal analysis and an understanding of the porosity and expansion penetration in cast iron.

The tensile strength of grey cast iron has been discussed by examining the fracture mechanism of the material at failure. The ultimate tensile strength is a result of the intimate collaboration between the graphite flake and the primary phases. Several parameters, including the graphite morphology, carbon content, inoculation and cooling conditions influence the ultimate tensile strength by offseting the equilibrium between the major constituents, the graphite flakes embedded in the primary metallic matrix. A model to predict the ultimate tensile strength is developed based on the interpretation of the stress intensity behaviour in a eutectic cell.

The models developed for nucleation, eutectic growth and prediction of tensile strength were introduced into a casting simulation program. Mould filling, solidificauon, microstructure development and tensile strength of a complex. shaped cylinder head were simulated.

Place, publisher, year, edition, pages
Jönköping: Jönköping, 2004. 25 p.
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 871
Keyword
grey iron, nucleation, primary austenite, eutectic cell, growth rate, inoculation, thermal analysis
National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-23153 (URN)2557 (Local ID)91-7373-939-1 (ISBN)2557 (Archive number)2557 (OAI)
Public defence
2004-05-14, Föreläsningssal E 101, Ingenjörshögskolan, Jönköping, 10:00 (Swedish)
Opponent
Available from: 2009-10-07 Created: 2009-10-07 Last updated: 2013-01-09

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