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Fullerene-like Carbon Nitride: A New Carbon-based Tribological Coating
Carnegie Mellon University, Pittsburgh, PA, USA .ORCID iD: 0000-0003-3277-1945
Linköping University, Department of Physics, Chemistry and Biology, Thin Film Physics. Linköping University, The Institute of Technology.
Linköping University, Department of Physics, Chemistry and Biology, Thin Film Physics. Linköping University, The Institute of Technology.ORCID iD: 0000-0002-2837-3656
2008 (English)In: Tribology of Diamond-Like Carbon Films: Fundamentals and Applications, Springer, 2008, 1, 620-653 p.Chapter in book (Refereed)
Abstract [en]

In 1994, researchers at Linköping University discovered the fullerene-like allotrope of carbon nitride (FL-CNx) by using reactive magnetron sputtering in a nitrogen-containing atmosphere at rather low ion energy assistance. FL-CNx is a predominantly sp2-hybridized material with nitrogen structurally incorporated either substitutionally in a graphite sheet or in a pyridine-like manner, which initiates bending by formation of pentagons and cross-linking, respectively. The assumed nitrogen-induced cross-linkage between the sheets contributes considerably to the strength of FL-CNx by preventing interplanar slip. This results in an extremely fracture tough, elastic, and compliant material, which deforms by reversible bond rotation and bond angle deflection rather than slip and bond breaking.

Place, publisher, year, edition, pages
Springer, 2008, 1. 620-653 p.
Keyword [en]
carbon nitride, C3N4, CNx, fullerene-like, thin films, magnetron sputtering
National Category
Materials Engineering Physical Sciences
Identifiers
URN: urn:nbn:se:liu:diva-88527DOI: 10.1007/978-0-387-49891-1_24ISBN: 978-0-387-30264-5 (print)ISBN: e-978-0-387-49891-1 OAI: oai:DiVA.org:liu-88527DiVA: diva2:604681
Available from: 2013-02-11 Created: 2013-02-11 Last updated: 2016-08-31Bibliographically approved

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Broitman, EstebanNeihardt, JörgHultman, Lars

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CiteExportLink to record
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