liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Influence of the central metal on the crystal structures and electronic structures of biferrocene trinuclear complexes
Department of Chemistry, Anhui University, China.
Department of Chemistry, Anhui University, China.
Department of Chemistry, Anhui University, China.
Department of Chemistry, Anhui University, China.
Show others and affiliations
2011 (English)In: Polyhedron, ISSN 0277-5387, E-ISSN 1873-3719, Vol. 30, no 2, 279-283 p.Article in journal (Refereed) Published
Abstract [en]

Five metal-bridged biferrocene complexes of the Schiff-base ligand (HL = S-benzyl-N-(ferrocenyl-1-methyl-methylidene)dithiocarbazate) have been studied by single crystal X-ray diffraction and 57Fe Mössbauer spectroscopy. The crystal structures of the complexes show that the central metal ions are tetra-coordinated by two ligands in two modes: the central d8 transition metal ions (Ni2+, Pd2+, and Pt2+) are nearly square-planar coordinated and the d10 transition metal ions (Zn2+ and Cd2+) are tetrahedrally coordinated. Interestingly, the isomer shifts in 57Fe Mössbauer spectroscopy are also of two kinds: d8 transition metal ions (0.097–0.247 mm/s) and d10 transition metal ions (0.416–0.435 mm/s).

Place, publisher, year, edition, pages
Elsevier, 2011. Vol. 30, no 2, 279-283 p.
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:liu:diva-90566DOI: 10.1016/j.poly.2010.10.022OAI: oai:DiVA.org:liu-90566DiVA: diva2:613836
Available from: 2013-04-02 Created: 2013-04-02 Last updated: 2017-12-06

Open Access in DiVA

No full text

Other links

Publisher's full text

Authority records BETA

Zhang, Xuanjun

Search in DiVA

By author/editor
Zhang, Xuanjun
In the same journal
Polyhedron
Natural Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 87 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf