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Anion-p-Interaction-Directed Self-Assembly of Ag(I) Coordination Networks
Department of Chemistry and Multidisciplinary Research Center, Shantou University, Guangdong , China.
Department of Chemistry and Multidisciplinary Research Center, Shantou University, Guangdong, China .
Department of Chemistry and Multidisciplinary Research Center, Shantou University, Guangdong, China .
Department of Chemistry and Multidisciplinary Research Center, Shantou University, Guangdong, China.
2007 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 7, no 3, 485-487 p.Article in journal (Refereed) Published
Abstract [en]

Reactions of AgX with 2,4,6-tri(2-pyridyl)-1,3,5-trazine (tpt) yielded three 3D highly symmetric isostructural coordination polymers (X = ClO4-, BF4-, and PF6-) and a dimer (X = CF3COO-), respectively. In the coordination polymers, anion−π interactions are found between the multiatomic anions and tpt ligands. Systematic variation including synthetic methods, ratios of reactants, and solvents provides synthetic evidence proving that anion−π interactions play a decisive role in assembly of the coordination polymers.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2007. Vol. 7, no 3, 485-487 p.
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:liu:diva-90607DOI: 10.1021/cg0608256OAI: oai:DiVA.org:liu-90607DiVA: diva2:613865
Available from: 2013-04-02 Created: 2013-04-02 Last updated: 2017-12-06

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Zhang, Xuanjun

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