Anion-p-Interaction-Directed Self-Assembly of Ag(I) Coordination Networks
2007 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 7, no 3, 485-487 p.Article in journal (Refereed) Published
Reactions of AgX with 2,4,6-tri(2-pyridyl)-1,3,5-trazine (tpt) yielded three 3D highly symmetric isostructural coordination polymers (X = ClO4-, BF4-, and PF6-) and a dimer (X = CF3COO-), respectively. In the coordination polymers, anion−π interactions are found between the multiatomic anions and tpt ligands. Systematic variation including synthetic methods, ratios of reactants, and solvents provides synthetic evidence proving that anion−π interactions play a decisive role in assembly of the coordination polymers.
Place, publisher, year, edition, pages
American Chemical Society (ACS), 2007. Vol. 7, no 3, 485-487 p.
IdentifiersURN: urn:nbn:se:liu:diva-90607DOI: 10.1021/cg0608256OAI: oai:DiVA.org:liu-90607DiVA: diva2:613865