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Synthesis, crystal structure and NLO properties of a novel ruthenium(II) complex with unusual coordination mode
Department of Chemistry, Anhui University, China.
Department of Chemistry, Anhui University, China.
Department of Chemistry, Anhui University, China.
Department of Chemistry, Anhui University, China.
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2005 (English)In: Transition metal chemistry (Weinheim), ISSN 0340-4285, E-ISSN 1572-901X, Vol. 30, no 7, 778-785 p.Article in journal (Refereed) Published
Abstract [en]

A new Schiff base 4-[N-hydroxyethyl-N-(methyl)amino]benzaldehyde S-methyl dithiocarbazate (HL, where H is a dissociable proton) and the ruthenium complex [Ru(bpy)2L]PF6 (bpy = 2,2′-bipyridine) have been synthesized. The structural determinations of the ligand and its ruthenium complex, by X-ray crystallography, show that the ligand is coordinated as a monoanionic bidentate N, S-donor, forming a four-member chelate ring with a bite angle of 65.91°. The complex shows intense MLCT transitions in the visible region. Fluorescent and electrochemical properties have been also studied. The complex in DMF solution exhibited a strong two-photon absorption (t.p.a.) at 532 nm nanosecond laser pulses. The t.p.a. coefficient β, t.p.a. cross-section σ and the third-order optical nonlinearity χ(3) of the complex and the ligand have been determined by the Z-scan technique.

Place, publisher, year, edition, pages
Kluwer Academic Publishers, 2005. Vol. 30, no 7, 778-785 p.
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:liu:diva-90623DOI: 10.1007/s11243-005-4825-5OAI: oai:DiVA.org:liu-90623DiVA: diva2:613919
Available from: 2013-04-02 Created: 2013-04-02 Last updated: 2017-12-06

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Tian, Yu-peng

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