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Two novel two-photon polymerization initiators with extensive application prospects
Department of Chemistry, Anhui university, China.
Department of Chemistry, Anhui university, China.
State Key Laboratory of Crystal Materials, Shandong University, China.
State Key Laboratory of Crystal Materials, Shandong University, China.
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2004 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 388, no 4-6, 325-329 p.Article in journal (Refereed) Published
Abstract [en]

Two novel two-photon polymerization initiators, 10-ethyl-3-E-(4-(N,N-di-n-butylamino)styryl)phenothiazine 5 and 10-ethyl-3,7-E,E-bis(4-(N,N-di-n-butyl amino)styryl)phenothiazine 6, have been efficiently synthesized with room temperature solid phase Wittig reaction. Two initiators were found to exhibit good single-photon fluorescence emission and their quantum yields, lifetimes and solvent effects have been studied in detail. Two-photon fluorescence spectra were investigated under 800 nm fs laser pulse and two-photon absorption (TPA) cross-sections of the initiators have been evaluated by theoretical calculation.Two-photon initiating polymerization microfabrication experiments have been carried out and artificial defects were made and polymerization mechanism was also discussed.

Place, publisher, year, edition, pages
Elsevier, 2004. Vol. 388, no 4-6, 325-329 p.
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:liu:diva-90645DOI: 10.1016/j.cplett.2004.02.099OAI: oai:DiVA.org:liu-90645DiVA: diva2:614026
Available from: 2013-04-03 Created: 2013-04-03 Last updated: 2017-12-06

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Zhang, Xuanjun

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