Uncoordinated inorganic salt in 1D chain structure: formation of a novel supermolecule [HgBr2(ptz)]2 ·HgBr2 (ptz = phenothiazine)
2003 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 6, no 10, 1338-1340 p.Article in journal (Refereed) Published
A novel supermolecule [HgBr2(ptz)]2 · HgBr2 (ptz=phenothiazine) with uncoordinated inorganic salt HgBr2 presented in a 1D chain was prepared. The bulky ligand phenothiazine has unusual coordination mode with large steric inhibition perpendicular to the chain direction. The uncoordinated HgBr2 molecule was stabilized by multiple weak Hg⋯Br interactions and the whole structure was also stabilized by strong π–π interactions and N–H⋯Br hydrogen bonds to form 2D network.
Place, publisher, year, edition, pages
Elsevier, 2003. Vol. 6, no 10, 1338-1340 p.
Supermolecule; Coordination mode; 1D chain; Photoluminescence
IdentifiersURN: urn:nbn:se:liu:diva-90649DOI: 10.1016/j.inoche.2003.08.013OAI: oai:DiVA.org:liu-90649DiVA: diva2:614032