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Uncoordinated inorganic salt in 1D chain structure: formation of a novel supermolecule [HgBr2(ptz)]2 ·HgBr2 (ptz = phenothiazine)
Department of Chemistry, University of Science and Technology of China.
The State Key Laboratory of Crystal Materials, Shandong University, China.
Department of Chemistry, University of Science and Technology of China.
Department of Chemistry, University of Science and Technology of China.
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2003 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 6, no 10, 1338-1340 p.Article in journal (Refereed) Published
Abstract [en]

A novel supermolecule [HgBr2(ptz)]2 · HgBr2 (ptz=phenothiazine) with uncoordinated inorganic salt HgBr2 presented in a 1D chain was prepared. The bulky ligand phenothiazine has unusual coordination mode with large steric inhibition perpendicular to the chain direction. The uncoordinated HgBr2 molecule was stabilized by multiple weak Hg⋯Br interactions and the whole structure was also stabilized by strong π–π interactions and N–H⋯Br hydrogen bonds to form 2D network.

Place, publisher, year, edition, pages
Elsevier, 2003. Vol. 6, no 10, 1338-1340 p.
Keyword [en]
Supermolecule; Coordination mode; 1D chain; Photoluminescence
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:liu:diva-90649DOI: 10.1016/j.inoche.2003.08.013OAI: oai:DiVA.org:liu-90649DiVA: diva2:614032
Available from: 2013-04-03 Created: 2013-04-03 Last updated: 2017-12-06

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Zhang, Xuanjun

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