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Surprising behavior of NXO-peptides toward the lithium hydroxide solvolysis
Vienna University of Technology, Austria .
Vienna University of Technology, Austria .
Vienna University of Technology, Austria .
Linköping University, Department of Physics, Chemistry and Biology, Sensor Science and Molecular Physics. Linköping University, The Institute of Technology.
2013 (English)In: Tetrahedron Letters, ISSN 0040-4039, E-ISSN 1359-8562, Vol. 54, no 28, 3679-3682 p.Article in journal (Refereed) Published
Abstract [en]

An unexpected rearrangement of NXO peptides was observed during solvolysis of the methyl ester using lithium hydroxide as the base. It was found that the NXO-compounds rearranged into semioxamazide derivatives in which the ester is derived from the alcohol used as the reaction solvent.

Place, publisher, year, edition, pages
Elsevier , 2013. Vol. 54, no 28, 3679-3682 p.
Keyword [en]
Peptidomimetics, NXO-building blocks, L-Phenylalanine, Modified amino acids, Rearrangement
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-95945DOI: 10.1016/j.tetlet.2013.05.010ISI: 000320689000026OAI: oai:DiVA.org:liu-95945DiVA: diva2:641757
Note

Funding Agencies|Higher Education Commission (HEC) of Pakistan||

Available from: 2013-08-19 Created: 2013-08-12 Last updated: 2017-12-06

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Phopase, Jaywant

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