liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Electron/phonon coupling in group-IV transition-metal and rare-earth nitrides
University of Illinois, IL 61801 USA .
University of Illinois, IL 61801 USA .
Linköping University, Department of Physics, Chemistry and Biology, Thin Film Physics. Linköping University, The Institute of Technology.ORCID iD: 0000-0002-2837-3656
University of Illinois, IL 61801 USA .
Show others and affiliations
2013 (English)In: Journal of Applied Physics, ISSN 0021-8979, E-ISSN 1089-7550, Vol. 114, no 19, p. 193708-Article in journal (Refereed) Published
Abstract [en]

Transport electron/phonon coupling parameters and Eliashberg spectral functions alpha F-2(tr)((h) over bar omega) are determined for group-IV transition-metal (TM) nitrides TiN, ZrN, and HfN, and the rare-earth (RE) nitride CeN using an inversion procedure based upon temperature-dependent (4 andlt; T andlt; 300 K) resistivity measurements of high-crystalline-quality stoichiometric epitaxial films grown on MgO(001) by magnetically-unbalanced reactive magnetron sputtering. Transport electron/phonon coupling parameters lambda(tr) vary from 1.11 for ZrN to 0.82 for HfN, 0.73 for TiN, and 0.44 for CeN. The small variation in lambda(tr) among the TM nitrides and the weak coupling in CeN are consistent with measured superconducting transition temperatures 10.4 (ZrN), 9.18 (HfN), 5.35 (TiN), and andlt; 4 K for CeN. The Eliashberg spectral function describes the strength and energy spectrum of electron/phonon coupling in conventional superconductors. Spectral peaks in alpha F-2(andlt;(h)over barandgt;omega), corresponding to regions in energy-space for which electrons couple to acoustic (h) over bar omega(ac) and optical (h) over bar omega(op) phonon modes, are centered at (h) over bar omega(ac) = 33 and (h) over bar omega(op) = 57 meV for TiN, 25 and 60 meV for ZrN, 18 and 64 meV for HfN, and 21 and 39 meV for CeN. The acoustic modes soften with increasing cation mass; optical mode energies remain approximately constant for the TM nitrides, but are significantly lower for the RE nitride due to a lower interatomic force constant. Optical/acoustic peak-intensity ratios are 1.15 +/- 0.1 for all four nitrides, indicating similar electron/phonon coupling strengths alpha(tr)((h) over bar omega) for both modes.

Place, publisher, year, edition, pages
American Institute of Physics (AIP) , 2013. Vol. 114, no 19, p. 193708-
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-102778DOI: 10.1063/1.4832778ISI: 000327592400028OAI: oai:DiVA.org:liu-102778DiVA, id: diva2:683900
Note

Funding Agencies|Swedish Research Council (VR)||Swedish Government Strategic Research Area Grant in Materials Science (SFO Mat-LiU) on Advanced Functional Materials||

Available from: 2014-01-07 Created: 2013-12-26 Last updated: 2017-12-06

Open Access in DiVA

fulltext(792 kB)754 downloads
File information
File name FULLTEXT01.pdfFile size 792 kBChecksum SHA-512
dc6242bf02422165bea70c44a0e81856507664b0523e629055eba1daedf11a0ab2b562dd87de2bba8f217dd3dc646ac44a0e50c3c5d7e170ed4852629a21b4a2
Type fulltextMimetype application/pdf

Other links

Publisher's full text

Authority records

Hultman, Lars

Search in DiVA

By author/editor
Hultman, Lars
By organisation
Thin Film PhysicsThe Institute of Technology
In the same journal
Journal of Applied Physics
Engineering and Technology

Search outside of DiVA

GoogleGoogle Scholar
Total: 754 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 243 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf