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Iron (III) Ion Sensor Based on the Seedless Grown ZnO Nanorods in 3 Dimensions Using Nickel Foam Substrate
Linköping University, Department of Science and Technology, Physics and Electronics. Linköping University, The Institute of Technology.
Linköping University, Department of Science and Technology, Physics and Electronics. Linköping University, The Institute of Technology.
National Centre for Physics, Islamabad, Pakistan .
Linköping University, Department of Science and Technology. Linköping University, The Institute of Technology.
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2013 (English)In: Journal of Sensors, ISSN 1687-725X, E-ISSN 1687-7268, no 382726Article in journal (Refereed) Published
Abstract [en]

In the present work, the seedless, highly aligned and vertical ZnO nanorods in 3 dimensions (3D) were grown on the nickel foam substrate. The seedless grown ZnO nanorods were characterised by field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), and X-ray diffraction (XRD) techniques. The characterised seedless ZnO nanorods in 3D on nickel foam were highly dense, perpendicular to substrate, grown along the (002) crystal plane, and also composed of single crystal. In addition to this, these seedless ZnO nanorods were functionalized with trans-dinitro-dibenzo-18-6 crown ether, a selective iron (III) ion ionophore, along with other components of membrane composition such as polyvinyl chloride (PVC), 2-nitopentylphenyl ether as plasticizer (NPPE), and tetrabutyl ammonium tetraphenylborate (TBATPB) as conductivity increaser. The sensor electrode has shown high linearity with a wide range of detection of iron (III) ion concentrations from 0.005 mM to 100 mM. The low limit of detection of the proposed ion selective electrode was found to be 0.001 mM. The proposed sensor also described high storage stability, selectivity, reproducibility, and repeatability and a quick response time of less than 10 s.

Place, publisher, year, edition, pages
Hindawi Publishing Corporation, 2013. no 382726
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-105432DOI: 10.1155/2013/382726ISI: 000331807400001OAI: oai:DiVA.org:liu-105432DiVA: diva2:706623
Available from: 2014-03-21 Created: 2014-03-21 Last updated: 2017-12-05

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Abbasi, Mazhar AliHussain Ibupoto, ZafarKhan, AzamNur, OmerWillander, Magnus

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