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NHC Copper(I) Complexes Bearing Dipyridylamine Ligands: Synthesis, Structural, and Photoluminescent Studies
University of Caen Basse Normandie, France.
CEA, France.
Linköping University, Department of Physics, Chemistry and Biology, Computational Physics. Linköping University, The Institute of Technology.
University of Caen Basse Normandie, France.
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2014 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 53, no 17, 9181-9191 p.Article in journal (Refereed) Published
Abstract [en]

We describe the synthesis of new cationic tricoordinated copper complexes bearing bidentate pyridine-type ligands and N-heterocyclic carbene as ancillary ligands. These cationic copper complexes were fully characterized by NMR, electrochemistry, X-ray analysis, and photophysical studies in different environments. Density functional theory calculations were also undertaken to rationalize the assignment of the electronic structure and the photophysical properties. These tricoordinated cationic copper complexes possess a stabilizing CH-pi interaction leading to high stability in both solid and liquid states. In addition, these copper complexes, bearing dipyridylamine ligands having a central nitrogen atom as potential anchoring point, exhibit very interesting luminescent properties that render them potential candidates for organic light-emitting diode applications.

Place, publisher, year, edition, pages
American Chemical Society , 2014. Vol. 53, no 17, 9181-9191 p.
National Category
Physical Sciences
URN: urn:nbn:se:liu:diva-111274DOI: 10.1021/ic501230mISI: 000341229600043PubMedID: 25134011OAI: diva2:755544

Funding Agencies|Ministere de la Recherche et des Nouvelles Technologies, Centre National de la Recherche Scientifique (CNRS); Agence Nationale de la Recherche [ANR-12-SECU-0002-02]; Region Basse-Normandie; LABEX SynOrg [ANR-11-LABX-0029]; SeRC (Swedish e-Science Research Center)

Available from: 2014-10-14 Created: 2014-10-14 Last updated: 2014-10-14

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Di Meo, FlorentLinares, Mathieu
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