Effects of ultraviolet soaking on surface electronic structures of solution processed ZnO nanoparticle films in polymer solar cells
2014 (English)In: Journal of Materials Chemistry A, ISSN 2050-7488, Vol. 2, no 41, 17676-17682 p.Article in journal (Refereed) Published
We systematically show the effect of UV-light soaking on surface electronic structures and chemical states of solution processed ZnO nanoparticle (ZnONP) films in UHV, dry air and UV-ozone. UV exposure in UHV induces a slight decrease in work function and surface-desorption of chemisorbed oxygen, whereas UV exposure in the presence of oxygen causes an increase in work function due to oxygen atom vacancy filling in the ZnO matrix. We demonstrate that UV-light soaking in combination with vacuum or oxygen can tune the work function of the ZnONP films over a range exceeding 1 eV. Based on photovoltaic performance and diode measurements, we conclude that the oxygen atom vacancy filling occurs mainly at the surface of the ZnONP films and that the films consequently retain their n-type behavior despite a significant increase in the measured work function.
Place, publisher, year, edition, pages
Royal Society of Chemistry , 2014. Vol. 2, no 41, 17676-17682 p.
Physical Sciences Biological Sciences
IdentifiersURN: urn:nbn:se:liu:diva-112033DOI: 10.1039/c4ta02695kISI: 000342763300057OAI: oai:DiVA.org:liu-112033DiVA: diva2:763906
Funding Agencies|EU ; Swedish Research Council Linnaeus grant LiLi-NFM2014-11-172014-11-132015-06-05