liu.seSearch for publications in DiVA
Change search
ReferencesLink to record
Permanent link

Direct link
Control of film morphology by folding hydrogen-bonded oligo(p-phenylenevinylene) polymers in solution
Eindhoven University of Technology, Netherlands.
Eindhoven University of Technology, Netherlands.
Linköping University, Department of Physics, Chemistry and Biology, Chemical and Optical Sensor Systems. Linköping University, The Institute of Technology.ORCID iD: 0000-0002-7104-7127
Eindhoven University of Technology, Netherlands.
Show others and affiliations
2006 (English)In: Macromolecules, ISSN 0024-9297, E-ISSN 1520-5835, Vol. 39, no 2, 784-788 p.Article in journal (Refereed) Published
Abstract [en]

The film morphology of pi-conjugated oligomers has been controlled by self-assembly in solution. To this end supramolecular hydrogen-bonded systems of oligo(p-phenylenevinylene) (OPV) carrying ureido-s-triazine hydrogen-bonding groups are used. Neutron scattering experiments in dodecane solutions show that columnar stacks are formed. Films with thicknesses on the order of 100 nm are made that have a supramolecular organization resembling the organization present in solution. Uniform rodlike morphological domains range over several hundreds of nanometers as shown by atomic force microscopy. The rodlike morphology of the OPVs was also preserved when blended with a C-60 derivative, producing stable photovoltaic devices.

Place, publisher, year, edition, pages
American Chemical Society , 2006. Vol. 39, no 2, 784-788 p.
National Category
Physical Sciences
URN: urn:nbn:se:liu:diva-118202DOI: 10.1021/ma0520085ISI: 000235004900042OAI: diva2:813493
Available from: 2015-05-22 Created: 2015-05-22 Last updated: 2015-06-01

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Kemerink, Martijn
By organisation
Chemical and Optical Sensor SystemsThe Institute of Technology
In the same journal
Physical Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 40 hits
ReferencesLink to record
Permanent link

Direct link