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Electronic Structure of Metal/Polymer Interfaces: Aluminum on Conjugated Polymers
Service de Chimie des Matériaux Nouveaux, Département des Matériaux et Procédés, Université de Mons-Hainaut, Belgium.
Service de Chimie des Matériaux Nouveaux, Département des Matériaux et Procédés, Université de Mons-Hainaut, Belgium.
Laboratoire Interdépartemental de Spectroscopie Electronique, Facultés Universitaires Notre-Dame de la Paix, Namur, Belgium.
Laboratoire Interdépartemental de Spectroscopie Electronique, Facultés Universitaires Notre-Dame de la Paix, Namur, Belgium .
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1991 (English)In: Metallized Plastics 2: Fundamental and Applied Aspects / [ed] Kashmiri Lal Mittal, Springer, 1991, 199-212 p.Chapter in book (Other academic)Text
Abstract [en]

Aluminum has been deposited on two types of conjugated polymers, polyalkylthiophene and polyaniline. The polymers were in the undoped, neutral form which possesses semiconducting properties. The chemical structure of the metal/polymer interface has been investigated by X-ray and UV photoelectron spectroscopy. Core level spectra indicate that aluminum reacts with the sulfur atom of the polythiophene chain, strongly perturbing the π-electron system. In the case of polyaniline, the interaction with the metal depends on the oxidation state of the polymer. UPS data, combined with the results of band structure calculations, are interpreted in terms of the Al-induced modifications of the π-electron system.

Place, publisher, year, edition, pages
Springer, 1991. 199-212 p.
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-124047DOI: 10.1007/978-1-4899-0735-6_16ISBN: 978-1-4899-0737-0 (Print)ISBN: 978-1-4899-0735-6 (Online)OAI: oai:DiVA.org:liu-124047DiVA: diva2:895345
Available from: 2016-01-18 Created: 2016-01-18 Last updated: 2016-01-28Bibliographically approved

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Uvdal, KajsaSalaneck, William R.
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Department of Physics, Chemistry and BiologyFaculty of Science & Engineering
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