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A Two-Dimensional Zirconium Carbide by Selective Etching of Al3C3 from Nanolaminated Zr3Al3C5
Chinese Academic Science, Peoples R China.
Chinese Academic Science, Peoples R China.
Chinese Academic Science, Peoples R China.
Chinese Academic Science, Peoples R China.
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2016 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 55, no 16, 5008-5013 p.Article in journal (Refereed) Published
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Abstract [en]

The room-temperature synthesis of a new two-dimensional (2D) zirconium-containing carbide, Zr3C2Tz MXene is presented. In contrast to traditional preparation of MXene, the layered ternary Zr3Al3C5 material instead of MAX phases is used as source under hydrofluoric acid treatment. The structural, mechanical, and electronic properties of the synthesized 2D carbide are investigated, combined with first-principles density functional calculations. A comparative study on the structrual stability of our obtained 2D Zr3C2Tz and Ti3C2Tz MXenes at elevated temperatures is performed. The obtained 2D Zr3C2Tz exhibits relatively better ability to maintain 2D nature and strucural integrity compared to Ti-based Mxene. The difference in structural stability under high temperature condition is explained by a theoretical investigation on binding energy.

Place, publisher, year, edition, pages
Wiley-Blackwell, 2016. Vol. 55, no 16, 5008-5013 p.
Keyword [en]
carbides; layered structures; nanosheets; selective extraction; thermal stability
National Category
Physical Sciences
Identifiers
URN: urn:nbn:se:liu:diva-127775DOI: 10.1002/anie.201510432ISI: 000374496100024PubMedID: 26959082OAI: oai:DiVA.org:liu-127775DiVA: diva2:927623
Note

Funding Agencies|National Natural Science Foundation of China [91226202, 91426304]; Chinese Academy of Sciences [XDA02040105, XDA03010305]; CAS Interdisciplinary Innovation Team Project; Ministry of Science and Technology of China [2015ZX06004-001]

Available from: 2016-05-12 Created: 2016-05-12 Last updated: 2016-06-08

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CiteExportLink to record
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