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Venting temperature determines surface chemistry of magnetron sputtered TiN films
Linköping University, Department of Physics, Chemistry and Biology, Thin Film Physics. Linköping University, Faculty of Science & Engineering. Rhein Westfal TH Aachen, Germany.ORCID iD: 0000-0002-4898-5115
Rhein Westfal TH Aachen, Germany.
Linköping University, Department of Physics, Chemistry and Biology, Thin Film Physics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0002-2837-3656
Rhein Westfal TH Aachen, Germany.
2016 (English)In: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 108, no 4, 041603-1-041603-5 p.Article in journal (Refereed) Published
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Abstract [en]

Surface properties of refractory ceramic transition metal nitride thin films grown by magnetron sputtering are essential for resistance towards oxidation necessary in all modern applications. Here, typically neglected factors, including exposure to residual process gases following the growth and the venting temperature T-v, each affecting the surface chemistry, are addressed. It is demonstrated for the TiN model materials system that T-v has a substantial effect on the composition and thickness-evolution of the reacted surface layer and should therefore be reported. The phenomena are also shown to have impact on the reliable surface characterization by x-ray photoelectron spectroscopy. (C) 2016 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.

Place, publisher, year, edition, pages
American Institute of Physics (AIP), 2016. Vol. 108, no 4, 041603-1-041603-5 p.
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Materials Chemistry
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URN: urn:nbn:se:liu:diva-128766DOI: 10.1063/1.4940974ISI: 000375217200010OAI: oai:DiVA.org:liu-128766DiVA: diva2:931801
Note

Funding Agencies|German Research Foundation (DFG) [SFB-TR 87]; VINN Excellence Center Functional Nanoscale Materials (FunMat) [2005-02666]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University [SFO-Mat-LiU 2009-00971]; Knut and Alice Wallenberg Foundation [2011.0143]

Available from: 2016-05-30 Created: 2016-05-30 Last updated: 2017-11-30

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Greczynski, GrzegorzHultman, Lars

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