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  • 1.
    Bittoun, Eyal
    et al.
    Technion Israel Institute Technology.
    Marmur, Abraham
    Technion Israel Institute Technology.
    Östblom, Mattias
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Ederth, Thomas
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Liedberg, Bo
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Filled Nanoporous Surfaces: Controlled Formation and Wettability2009Ingår i: LANGMUIR, ISSN 0743-7463, Vol. 25, nr 20, s. 12374-12379Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The controlled filling of hydrophobic nanoporous surfaces with hydrophilic molecules and their wetting properties are described and demonstrated by using thiocholesterol (TC) self-assembled monolayers (SAMs) on gold and mercaptoundecanoic acid (MUA) as the filling agent. A novel procedure was developed for filling the nanopores in the TC SAMs by immersing them into a "cocktail" solution of TC and MUA, with TC in huge excess. This procedure results in an increasing coverage of MUA with increasing immersion time up to an area fraction of similar to 23%, while the amount of TC remains almost constant. Our findings strongly support earlier observations where linear omega-substituted alkanethiols selectively fill defects (nanopores) in the TC SAM (Yang et al. Langmuir 1997, 12, 1704-1707). They also support the formation of a homogeneously mixed SAM, given by the distribution of TC on the gold surface, rather than of a phase-segregated overlayer structure with domains of varying size, shape, and composition. The wetting properties of the Filled SAMs were investigated by measuring the most stable contact angle as well as contact angle hysteresis. It is shown that the most stable contact angle is very well described by the Cassie equation, since the drops arc much larger than the scale of chemical heterogeneity of the SAM surfaces. In addition, it is demonstrated that contact angle hysteresis is sensitive to the chemical heterogeneity of the surface, even at the nanometric scale.

  • 2. Demers, LM
    et al.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Zhang, Hanmin
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Jang, NH
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Mirkin, CA
    Thermal desorption behavior and binding properties of DNA bases and nucleosides on gold2002Ingår i: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 124, nr 38, s. 11248-11249Artikel i tidskrift (Refereegranskat)
  • 3.
    Ederth, Thomas
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Nygren, Patrik
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Ekblad, Tobias
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Östblom, Mattias
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Liedberg, Bo
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Pettitt, M.E.
    The University of Birmingham, School of Biosciences, Birmingham, UK.
    Callow, M.E.
    The University of Birmingham, School of Biosciences, Birmingham, UK.
    Callow, J.A.
    The University of Birmingham, School of Biosciences, Birmingham, UK.
    Interactions of algal spores and diatoms with mixed synthetic peptide SAMs2007Konferensbidrag (Övrigt vetenskapligt)
  • 4. Hellgren, N.
    et al.
    Johansson, Mats P
    Hjorvarsson, B.
    Hjörvarsson, B., Materials Physics, Royal Institute of Technology, Teknikringen 14, S-100 44 Stockholm, Sweden.
    Broitman, E.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Hultman, Lars
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik.
    Sundgren, J.-E.
    Growth, structure, and mechanical properties of CNxHy films deposited by dc magnetron sputtering in N2/Ar/H2 discharges2000Ingår i: Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films, ISSN 0734-2101, E-ISSN 1520-8559, Vol. 18, nr 5, s. 2349-2358Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Reactive direct current magnetron sputtering was used to deposit the hydrogenated carbon nitride films in mixed nitrogen (N2)/argon (Ar)/ hydrogen (H2) discharges. Growth and structure evolution of films was found to be affected by chemical sputtering effects. The hydrogen were found to be bonded to nitrogen and hydrogen incorporation decreases the elasticity and hardness.

  • 5.
    Li, Wei
    et al.
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för medicin och hälsa.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Xu, Lihua
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för klinisk och experimentell medicin, Experimentell patologi.
    Hellsten, A.
    Leanderson, Per
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för klinisk och experimentell medicin, Yrkes- och miljömedicin. Östergötlands Läns Landsting, Medicincentrum, Smärt- och rehabiliteringscentrum.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Brunk, Ulf
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för medicin och hälsa, Farmakologi.
    Eaton, J.W.
    James Graham Brown Cancer Center, University of Louisville, Louisville, KY, United States.
    Yuan, Ximing
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för klinisk och experimentell medicin.
    Cytocidal effects of atheromatous plaque components: The death zone revisited2006Ingår i: The FASEB Journal, ISSN 0892-6638, E-ISSN 1530-6860, Vol. 20, nr 13, s. 2281-2290Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Objective: Earlier we suggested that atheroma lesions constitute a "death zone" containing toxic materials that may cause dysfunction and demise of invading macrophages to prevent the removal of plaque materials. Here we have assessed the cytotoxic effects of nonfractionated gruel and insoluble (ceroid-like) material derived from advanced human atheroma. Methods and Results: The insoluble material within advanced atherosclerotic plaque was isolated following protease K digestion and extensive extraction with aqueous and organic solvents. FTIR, Raman, and atomic absorption spectroscopy suggested that, despite its fluorescent nature, this material closely resembled hydroxyapatite and dentin, but also contained a significant amount of iron and calcium. When added to J774 cells and human macrophages in culture, this insoluble substance was phagocytosed, and progressive cell death followed. However, an even more cytotoxic activity was found in the atheromatous "gruel" that contains abundant carbonyls/aldehydes. Cell death caused by both crude gruel and ceroid could be blocked by preincubating cells with the lipophilic iron chelator salicylaldehyde isonicotinoyl hydrazone, apoferritin, BAPTA/AM, or sodium borohydride, indicating that cellular iron, calcium, and reactive aldehyde(s) are responsible for the observed cytotoxicity. Conclusions: Toxic materials within atheromatous lesions include both ceroid and even more cytotoxic lipidaceous materials. The cytotoxic effects of these plaque components may help explain the persistence of atherosclerotic lesions. © FASEB.

  • 6.
    Li, Wei
    et al.
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för nervsystem och rörelseorgan, Patologi.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Xu, Lihua
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för nervsystem och rörelseorgan, Patologi.
    Hellsten, Anna
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för biomedicin och kirurgi.
    Leanderson, Per
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för molekylär och klinisk medicin, Yrkes- och miljömedicin. Östergötlands Läns Landsting, Smärt- och yrkesmedicinskt centrum, Yrkes- och miljömedicinskt centrum.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Brunk, Ulf
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för medicin och vård, Farmakologi.
    Eaton, John Wallace
    USA .
    Yuan, Xi Ming
    Linköpings universitet, Hälsouniversitetet. Linköpings universitet, Institutionen för nervsystem och rörelseorgan, Patologi.
    Cytocidal effects of atheromatous plaque components: the death zone revisited.2006Ingår i: The FASEB Journal, ISSN 0892-6638, E-ISSN 1530-6860, Vol. 20, s. 2281-2290Artikel i tidskrift (Refereegranskat)
    Abstract [en]

       

  • 7.
    Music, Denis
    et al.
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik.
    Schneider, Jochen
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Kugler, Veronika Mozhdeh
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Nakao, S.
    National Industrial Research Institute of Nagoya, Nagoya 462-8510, Japan.
    Jin, P.
    National Industrial Research Institute of Nagoya, Nagoya 462-8510, Japan.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Hultman, Lars
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik.
    Helmersson, Ulf
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Plasma och beläggningsfysik.
    Synthesis and mechanical properties of boron suboxide thin films2002Ingår i: Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films, ISSN 0734-2101, E-ISSN 1520-8559, Vol. 20, nr 2, s. 335-337Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The synthesis and mechanical properties of boron suboxide thin films deposited on silicon and graphite substrates was discussed. The deposition was performed using reactive magnetron sputtering technique, and amorphous films were obtained. The affect of varying O2 partial pressure on film composition and microstructure was studied using spectroscopic techniques. It was found that variation of partial pressure from 0.02 to 0.21 resulted in a decrease in elastic modulus from 272 to 109 GPa.

  • 8. Riepl, M.
    et al.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Lundström, Ingemar
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Tillämpad Fysik.
    Svensson, S.C.T.
    Van, Der Gon A.W.D.
    Van Der Gon, A.W.D., Advalytix AG, Eugen-Sänger-Ring 4, D-85649 Brunnthal-Nord, Germany, Faculty of Applied Physics, Eindhoven University of Technology, 5600 MB Eindhoven, Netherlands.
    Schaferling, M.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Molecular gradients: An efficient approach for optimizing the surface properties of biomaterials and biochips2005Ingår i: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 21, nr 3, s. 1042-1050Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    A variety of molecular gradients of alkanethiols with the structure HS-(CH2)m-X (m = 15, X = COOH, CH2NH 2, or CH3) and oligo(ethylene glycol)-terminated alkanethiols with the structures HS-(CH2)15-CO-NH-Eg n (n = 2, 4, or 6), HS-(CH2)15-CO-NH-Eg 2-(CH2)2-NH-CO-(CH2) 4-biotin, and HS-(CH2)15-CO-NH-Eg 6-CH2-COOH were prepared on polycrystalline gold films. These gradients were designed to serve as model surfaces for fundamental studies of protein adsorption and immobilization phenomena. Ellipsometry, infrared spectroscopy, and X-ray photoelectron spectroscopy, operating in scanning mode, were used to monitor the layer composition, gradient profiles, tail group conformation, and overall structural quality of the gradient assemblies. The gradient profiles were found to be 4-10 mm wide, and they increased in width with increasing difference in molecular complexity between the thiols used to form the gradient. The oligo(ethylene glycol) thiols are particularly interesting because they can be used to prepare so-called conformational gradients, that is, gradients that display a variation in oligo(ethylene glycol) chain conformation from all trans on the extreme Eg 2,4 sides, via an amorphous-like phase in the mixing regimes, to helical at the extreme Eg6 sides. We demonstrate herein a series of experiments where the above gradients are used to evaluate nonspecific binding of the plasma protein fibrinogen, and in agreement with previous studies, the highest amounts of nonspecifically bound fibrinogen were observed on all-trans monolayers, that is, on the extreme Eg2,4 sides. Moreover, gradients between Eg2 and a biotinylated analogue have been prepared to optimize the conditions for the immobilization of streptavidin. Ellipsometry and infrared spectroscopy reveal high levels of immobilization over a fairly broad range of compositions in the gradient regime, with a maximum between 50 and 60% of the biotinylated analogue in the monolayer. A pi gradient composed of (NH3+/COO-)-terminated thiols was also prepared and evaluated with respect to its ability to separate differently charged proteins, pepsin, and lysozyme, on a solid surface.

  • 9.
    Valiokas, Ramunas
    et al.
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Svedhem, S
    Linkoping Univ, Dept Phys & Measurement Technol, Grad Sch Forum Scientum, S-58183 Linkoping, Sweden Univ Uppsala, Dept Phys, Uppsala, Sweden.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Gelius, U
    Linkoping Univ, Dept Phys & Measurement Technol, Grad Sch Forum Scientum, S-58183 Linkoping, Sweden Univ Uppsala, Dept Phys, Uppsala, Sweden.
    Svensson, SCT
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Tunable phases of oligo(ethylene glycol) in self-assembled monolayers and their use as support for lipid bilayers.2000Ingår i: Abstract of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 219, s. 397-COLL-Konferensbidrag (Övrigt vetenskapligt)
  • 10.
    Valiokas, Ramunas
    et al.
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Svedhem, S.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Svensson, Stefan
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Organisk Kemi.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Influence of specific intermolecular interactions on the self-assembly and phase behavior of oligo(ethylene glycol)-terminated alkanethiolates on gold2001Ingår i: Journal of Physical Chemistry B, ISSN 1089-5647, Vol. 105, nr 23, s. 5459-5469Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    A comparative study of the self-assembly and phase behavior of seven different oligo(ethylene glycol) (OEG)-terminated alkanethiols on polycrystalline gold surfaces is presented. The general structure of the compounds is HS(CH2)m-X-EGn, where m = 11, 15, n = 2, 4, 6, and the linkages X are amide (-CONH-), ester (-COO-), or ether (-O-) groups. The amide and ester groups give rise to the intermolecular hydrogen bonding and dipole-dipole interactions, respectively, whereas the ether lacks specific interactions. The results from contact angle goniometry, null ellipsometry, and infrared reflection-absorption spectroscopy (IRAS) indicate that the intermolecular interactions can be partly used to control the conformation and order of the OEG portion of the self-assembled monolayers (SAMs). It is shown that the lateral hydrogen bonding stabilizes the all-trans conformation of the EG4 tails in the SAMs. Further on, the mechanism behind the thermal phase behavior of the OEG SAMs is investigated using temperature-programmed IRAS in ultrahigh vacuum. In the present study we show that the earlier reported helix-to-all-trans conformational transition at 60°C in the SAM of HS(CH2)15CONH-EG6 (Valiokas, R., Östblom, M., Svedhem, S., Svensson, S. C. T., Liedberg, B. J. Phys. Chem. 2000, 104, 7565-7569.) is a result of the particular molecular design of the SAMs through the specifically built-in lateral hydrogen bonds. A shortening of the alkyl chain to 11 methylenes has no effect on the amide-EG6 phase behavior. Contrary, the ester- and ether- containing SAMs undergo a melting type of transitions at 52 and 68°C, respectively, similar to that observed for poly(ethylene glycol).

  • 11.
    Valiokas, Ramunas
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi. Linköpings universitet, Tekniska högskolan.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Björefors, Fredrik
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Shi, Jing
    Linköpings universitet, Institutionen för fysik, kemi och biologi. Linköpings universitet, Tekniska högskolan.
    Konradsson, Peter
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Organisk Kemi.
    Structural and kinetic properties of laterally stabilized, oligo(ethylene glycol)-containing alkylthiolates on gold: A modular approach2006Ingår i: Biointerphases, ISSN 1934-8630, E-ISSN 1559-4106, Vol. 1, nr 1, s. 22-34Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The formation of highly ordered self-assembled monolayers (SAMs) on goldfrom an unusually long and linear compound HS(CH2)15CONH(CH2CH2O)6CH2CONH(CH2)15CH3 is investigated by contact angle goniometry, ex situ null ellipsometry, cyclic voltammetry and infrared reflection-absorption spectroscopy. The molecules are found to assemble in an upright position as a complete monolayer within 60 min. The overall structure of the SAM reaches equilibrium within 24 h as evidenced by infrared spectroscopy, although a slight improvement in water contact angles is observed over a period of a few weeks. The resulting SAM is 60 Å thick and it displays an advancing water contact angle of 112° and excellent electrochemicalblocking characteristics with typical current densities about 20 times lower as compared to those observed for HS(CH2)15CH3 SAMs. The dominating crystalline phases of the supporting HS(CH2)15 and terminal (CH2)15CH3 alkyl portions, as well as the sealed oligo(ethylene glycol) (OEG) “core,” appear as unusually sharp features in the infrared spectra at room temperature. For example, the splitting seen for the CH3 stretching and CH2 scissoring peaks is normally only observed for conformationally trapped alkylthiolate SAMs at low temperatures and for highly crystalline polymethylenes. Temperature-programmed infrared spectroscopy in ultrahigh vacuum reveals a significantly improved thermal stability of the SAM under investigation, as compared to two analogous OEG derivatives without the extended alkyl chain. Our study points out the advantages of adopting a “modular approach” in designing novel SAM-forming compounds with precisely positioned in plane stabilizing groups. We demonstrate also the potential of using the above set of compounds in the fabrication of “hydrogel-like” arrays with controlled wetting properties for application in the ever-growing fields of protein and cell analysis, as well as for bioanalytical applications.

  • 12.
    Valiokas, Ramunas
    et al.
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Östblom, Mattias
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Svedhem, S.
    Svensson, S.C.T.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Thermal stability of self-assembled monolayers: Influence of lateral hydrogen bonding2002Ingår i: Journal of Physical Chemistry B, ISSN 1089-5647, Vol. 106, nr 40, s. 10401-10409Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Temperature-programmed desorption (TPD) of self-assembled monolayers (SAMs) on gold is investigated by using in parallel mass spectrometry (MS) and infrared reflection-absorption spectroscopy (IRAS). Monolayers formed by HS(CH2)n-OH (n = 18, 22) and HS(CH2)15-CONH-(CH2CH2O)-H (EG1) are compared to reveal the influence of specifically introduced hydrogen-bonding groups on their thermal stability. The overall desorption process of the above molecules is found to occur in two main steps, a disordering of the alkyl chains followed by a complex series of decomposition/desorption reactions. The final step of the process involves desorption of sulfur from different chemisorption states. The amide-group-containing SAM, which is stabilized by lateral hydrogen bonds, displays a substantial delay of the alkyl chain disordering by about 50 K, as compared to the linear chain alcohols HS(CH2)n-OH. Moreover, the decomposition of the alkyls and the onset of sulfur desorption occur at a temperature that is higher by approximately 25 K as compared to the HS(CH2)18-OH SAM. The desorption process is also studied for two oligo(ethylene glycol)-terminated SAMs, HS(CH2)15-X-(CH2CH2O)4-H (EG4-SAMs), where X is -CONH- and -COO- linking groups. In addition to the molecular chain disordering, the decomposition/desorption process of the EG4-SAMs occurs in two steps. The first is associated with the loss of the oligomer portion and the second with the desorption of the alkylthiolate part of the molecule. Our study points out that lateral hydrogen bonding, introduced via amide groups, is a convenient way to improve the thermal stability of alkanthiolate SAMs.

  • 13.
    Valiokas, Ramunas
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi. Linköpings universitet, Tekniska högskolan.
    Östblom, Mattias
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Svedhem, Sofia
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Kemi. Linköpings universitet, Tekniska högskolan.
    Svensson, Stefan C. T.
    Linköpings universitet, Institutionen för fysik, kemi och biologi. Linköpings universitet, Tekniska högskolan.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Temperature-driven phase transitions in oligo(ethylene glycol)-terminated self-assembled monolayers2000Ingår i: The Journal of Physical Chemistry B, ISSN 1520-6106, Vol. 104, nr 32, s. 7565-7569Artikel i tidskrift (Övrigt vetenskapligt)
    Abstract [en]

    This letter explores the phase behavior of oligo(ethylene glycol) self-assembled monolayers using temperature-programmed infrared reflection absorption spectroscopy. The monolayers are formed by self-assembly of hexa(ethylene glycol) (EG(6)) and tetra(ethylene glycol) (EG(4))-terminated and amide group containing alkanethiols on polycrystalline gold. The ethylene glycol portions of the two monolayers are known to exist in two different conformations at room temperature: EG(6) in helical and EG(4) in all-trans (zigzag). The helical phase of the EG(6) gradually diminishes upon increasing the temperature and a pronounced conformational transition occurs around 60 degrees C, leading to a rapidly increasing population of all-trans conformers along the EG(6) chain. The EG(4) SAM exhibits a much simpler phase behavior. The oligomer conformation is marginally affected upon increasing the temperature to 75 degrees C, displaying the dominating all-trans phase, which possibly coexists with a small fraction of gauche-rich (disordered) regions. The reported conformational changes are reversible upon returning to 20 degrees C after stepwise heating to 70 degrees C.

  • 14.
    Wang, Xiangjun
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Biomolekylär och Organisk Elektronik. Linköpings universitet, Tekniska högskolan.
    Östblom, Mattias
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik. Linköpings universitet, Tekniska högskolan.
    Johansson, Tomas
    Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Inganäs, Olle
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Biomolekylär och Organisk Elektronik. Linköpings universitet, Tekniska högskolan.
    PEDOT surface energy pattern controls fluorescent polymer deposition by dewetting2004Ingår i: Thin Solid Films, ISSN 0040-6090, E-ISSN 1879-2731, Vol. 449, nr 1-2, s. 125-132Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    An elastomeric stamp of poly(dimethylsiloxane) (PDMS) can modify the surface energy of some surfaces when brought into conformal contact with these for some time. The substrates under investigation are a conducting polymer poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS) and a polyelectrolyte poly(sodium 4-styrenesulfonate) (NaPSS). The changes in surface wetting are characterized by contact angle measurement. Changes are due to the PDMS stamp, which leaves low molecular weight residues on the surface, as shown by infrared reflection absorption spectroscopy. This process may also be operating when other inks are transferred in microcontact printing. Patterning of fluorescent polymer film with feature size of 10–100 μm range is done by confining polymer solutions on the modified surface, by means of spin- or dip-coating. The profile of the patterned film and factors that influence the profile are discussed. This technique is a convenient way to build polymer microstructures for application in organic and biomolecular electronics and photonics.

  • 15.
    Östblom, Mattias
    et al.
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Ekeroth, Johan
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Konradsson, Peter
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Organisk Kemi.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Structure and desorption energetics of ultrathin D2O ice overlay ers on serine- And serinephosphate-terminated self-assembled monolayers2006Ingår i: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 110, nr 4, s. 1695-1700Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    This paper reports on the structure and desorption dynamics of thin D 2O ice overlayers (0.2-10 monolayers) deposited on serine- and serinephosphate- (with H+, Na+, Ca2+ counterions) terminated self-assembled monolayers (SAMs). The D2O ice overlayers are deposited on the SAMs at ~85 K in ultrahigh vacuum and characterized with infrared reflection absorption spectroscopy (IRAS). Reflection absorption (RA) spectra obtained at sub-monolayer D2O coverage reveal that surface modes, e.g. free dangling OD stretch, dominate on the serine SAM surface, whereas vibrational modes characteristic for bulk ice are more prominent on the serinephosphate SAMs. Temperature programmed desorption mass spectrometry (TPD-MS) and TPD-IRAS are subsequently used to investigate the energetics and the structural transitions occurring in the ice overlayer during temperature ramping. D2O ice (~2.5 monolayers) on the serine SAMs undergoes a gradual change from an amorphous- to a crystalline-like phase upon increasing the substrate temperature. This transition is not as pronounced on the serine phosphate SAM most likely because of reduced mobility due to strong pinning to the surface. We show also that the energy of desorption for a sub-monolayer of D2O ice on serinephosphate SAM surfaces with a Na+ and Ca2+ counterions is equally high or even exceeds previously reported values for analogous high-energy SAMs. © 2006 American Chemical Society.

  • 16.
    Östblom, Mattias
    et al.
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Demers, L.M.
    Department of Chemistry, Center for Nanofabrication and Molecular Self-Assembly, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208.
    Mirkin, C.A.
    Department of Chemistry, Center for Nanofabrication and Molecular Self-Assembly, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208.
    On the structure and desorption dynamics of DNA bases adsorbed on gold: A temperature-programmed study2005Ingår i: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 109, nr 31, s. 15150-15160Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The structure and desorption dynamics of mono- and multilayer samples of adenine, cytosine, guanine, and thymine on polycrystalline gold thin films are studied using temperature-programmed desorption-infrared reflection absorption spectroscopy (TPD-IRAS) and temperature-programmed desorption-mass spectroscopy (TPD-MS). It is shown that the pyrimidines, adenine and guanine, adsorb to gold in a complex manner and that both adhesive (adenine) and cohesive (guanine) interactions contribute the apparent binding energies to the substrate surface. Adenine displays at least two adsorption sites, including a high-energy site (210°C, ~136 kj/mol), wherein the molecule coordinates to the gold substrate via the NH2 group in an sp3-like, strongly perturbed, nonplanar configuration. The purines, cytosine and thymine, display a less complicated adsorption/desorption behavior. The desorption energy for cytosine (160°C, ~122 kJ/mol) is similar to those obtained for adenine and guanine, but desorption occurs from a single site of dispersed, nonaggregated cytosine. Thymine desorbs also from a single site but at a significantly lower energy (100°C, ~104 kJ/mol). Infrared data reveal that the monolayer architectures discussed herein are structurally very different from those observed for the bases in the bulk crystalline state. It is also evident that both pyrimidines and purines adsorb on gold with the plane of the molecule in a nonparallel orientation with respect to the substrate surface. The results of this work are discussed in the context of improving the understanding of the design of capturing oligonucleotides or DNA strands for bioanalytical applications, in particular, for gold nanoparticle-based assays. © 2005 American Chemical Society.

  • 17.
    Östblom, Mattias
    et al.
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Valiokas, Ramunas
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi.
    Konradsson, Peter
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Organisk Kemi.
    Svensson, Stefan
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Organisk Kemi.
    Liedberg, Bo
    Linköpings universitet, Tekniska högskolan. Linköpings universitet, Institutionen för fysik, kemi och biologi, Sensorvetenskap och Molekylfysik.
    Garrett, M.
    Department of Chemistry and Materials Science, Pennsylvania State University, University Park, PA 16802.
    Allara, D.L.
    Department of Chemistry and Materials Science, Pennsylvania State University, University Park, PA 16802.
    Ice nucleation and phase behavior on oligo(ethylene glycol) and hydroxyl self-assembled monolayers: Simulations and experiments2006Ingår i: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 110, nr 4, s. 1830-1836Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The nucleation and phase behavior of ultrathin D2O-ice overlayers have been studied on oligo(ethylene glycol) (OEG)-terminated and hydroxyl self-assembled monolayers (SAMs) at low temperatures in ultrahigh vacuum. Infrared reflection-absorption spectroscopy (IRAS) is used to characterize the ice overlayers, the SAMs, and the interactions occurring between the ice and the SAM surfaces. Spectral simulations, based on optical models in conjunction with Maxwell Garnett effective medium theory, point out the importance of including voids in the modeling of the ice structures, with void fractions reaching 60% in some overlayers. The kinetics of the phase transition from amorphous-like to crystalline-like ice upon isothermal annealing at 140 K is found to depend on the conformational state of the supporting OEG SAM surface. The rate is fast on the helical OEG SAMs and slow on the corresponding all-trans SAMs. This difference in kinetics is most likely due to a pronounced D2O interpenetration and binding to the all-trans segments of the ethylene glycol portion of the SAM. No such penetration and binding was observed on the helical OEG SAM. © 2006 American Chemical Society.

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