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  • 1.
    Klemenso, Trine
    et al.
    Technical University of Denmark.
    Nielsen, Jimmi
    Technical University of Denmark.
    Blennow, Peter
    Y`Technical University of Denmark.
    Persson, Asa H
    Technical University of Denmark.
    Stegk, Tobias
    Technical University of Denmark.
    Holl Christensen, Bjarke
    Danish Technology Institute.
    Sønderby, Steffen
    Linköpings universitet, Institutionen för fysik, kemi och biologi. Linköpings universitet, Tekniska högskolan.
    High performance metal-supported solid oxide fuel cells with Gd-doped ceria barrier layers2011Inngår i: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 196, nr 22, s. 9459-9466Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Metal-supported solid oxide fuel cells are believed to have commercial advantages compared to conventional anode (Ni-YSZ) supported cells, with the metal-supported cells having lower material costs, increased tolerance to mechanical and thermal stresses, and lower operational temperatures. The implementation of a metallic support has been challenged by the need to revise the cell fabrication route, as well as electrode microstructures and material choices, to compete with the energy output and stability of full ceramic cells. less thanbrgreater than less thanbrgreater thanThe metal-supported SOFC design developed at Riso DTU has been improved, and an electrochemical performance beyond the state-of-the-art anode-supported SOFC is demonstrated possible, by introducing a CGO barrier layer in combination with Sr-doped lanthanum cobalt oxide (LSC) cathode. Area specific resistances (ASR) down to 0.27 Omega cm(2), corresponding to a maximum power density of 1.14 W cm(-2) at 650 degrees C and 0.6 V. were obtained on cells with barrier layers fabricated by magnetron sputtering. The performance is dependent on the density of the barrier layer, indicating Sr(2+) diffusion is occurring at the intermediate SOFC temperatures. The optimized design further demonstrate improved durability with steady degradation rates of 0.9% kh(-1) in cell voltage for up to 3000 h galvanostatic testing at 650 degrees C and 0.25 A cm(-2).

  • 2.
    Lunca Popa, Petru
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Sønderby, Steffen
    Linköpings universitet, Institutionen för fysik, kemi och biologi. Linköpings universitet, Tekniska högskolan.
    Kerdsongpanya, S.
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Lu, Jun
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Bonanos, N.
    Technical University of Denmark, Denmark.
    Eklund, Per
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Highly oriented δ-Bi2O3 thin films stable at room temperature synthesized by reactive magnetron sputtering2013Inngår i: Journal of Applied Physics, ISSN 0021-8979, E-ISSN 1089-7550, Vol. 113, nr 4Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    We report the synthesis by reactive magnetron sputtering and structural characterization of highly (111)-oriented thin films of δ–Bi2O3. This phase is obtained at a substrate temperature of 150–200 °C in a narrow window of O2/Ar ratio in the sputtering gas (18%–20%). Transmission electron microscopy and x-ray diffraction reveal a polycrystalline columnar structure with (111) texture. The films are stable from room temperature up to 250 °C in vacuum and 350 °C in ambient air.

  • 3. Bestill onlineKjøp publikasjonen >>
    Sønderby, Steffen
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Physical Vapor Deposition of Yttria-Stabilized Zirconia and Gadolinia-Doped Ceria Thin Films for Fuel Cell Applications2012Licentiatavhandling, med artikler (Annet vitenskapelig)
    Abstract [en]

    In this thesis, reactive sputter deposition of yttria-stabilized zirconia (YSZ) and cerium gadolinium oxide (CGO) thin films for solid oxide fuel cell (SOFC) applications have been studied. All films have been deposited under industrial conditions.

    YSZ films were deposited on silicon wafers as well as commercial NiO-YSZ fuel cell anodes. The texture, morphology, and composition of the deposited films were investigated with respect to deposition parameters such as bias voltage which was identified as a key parameter to tailor the texture of the film and promote less columnar coatings when depositing on Si. In contrast, films grown on NiO-YSZ fuel cell anodes were seen to be randomly orientated when deposited at low substrate bias voltages. When the bias voltage was increased the film took over the orientation of underlying substrate due to substrate template effects. The deposited coatings were found to be homogeneous large areas within the coating zone, which is highly important for industrial applications.

    The performance of sputtered CGO thin films as diffusion barriers for stopping Sr diffusion between SOFC cathodes and electrolytes was also studied. This was done by introducing the sputtered CGO films in a metal-based SOFC setup. The performance depended on the density of the barrier layer, signifying that Sr diffusion and SrZrO3 formation is an issue. Area specific resistances down to 0.27 Ωcm2, corresponding to a maximum power density up to 1.14 W cm−2 at 650 °C could be obtained with sputtered CGO barrier layers in combination with Sr-doped lanthanum cobalt oxide cathodes which is a significant improvement compared conventional ceramic SOFCs.

    The diffusion mechanism of Sr through sputtered CGO films was investigated. For this purpose, a model system simulating a SOFC was prepared by depositing CGO and YSZ on cathode material. This setup allowed observation of Sr diffusion by observing SrZrO3 formation using X-ray diffraction while annealing. Electron microscopy was subsequently performed to confirm the results. It was found that Sr diffused along column/grain boundaries in the CGO films but by modifying the film thickness and microstructure the breaking temperature of the barrier could be increased.

    Delarbeid
    1. Reactive magnetron sputtering of uniform yttria-stabilized zirconia coatings in an industrial setup
    Åpne denne publikasjonen i ny fane eller vindu >>Reactive magnetron sputtering of uniform yttria-stabilized zirconia coatings in an industrial setup
    Vise andre…
    2012 (engelsk)Inngår i: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 206, nr 19-20, s. 4126-4131Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Yttria-stabilized zirconia (YSZ) thin films were deposited by reactive magnetron sputtering in an industrial scale setup on silicon wafers as well as commercial NiO-YSZ fuel cell anodes. The texture, morphology, and composition of the deposited films were investigated as a function of deposition parameters. Homogeneous coatings could be deposited over large areas within the coating zone, which is important for industrial applications. The use of substrate bias during film growth was identified as a key parameter to promote less columnar coatings and made it possible to tailor the texture of films deposited on Si. Bias voltages less than= - 40V resulted in highly less than 200 greater than textured YSZ films, intermediate bias voltages of - 50 V to - 70 V in less than 220 greater than textured films and high bias voltages (greater than= - 90 V) in a mixed orientation. In contrast, films grown on NiO-YSZ were seen to be randomly orientated when deposited at substrate bias voltages less than= - 30 V. When bias was further increased the film took over the orientation of underlying substrate due to substrate template effects.

    sted, utgiver, år, opplag, sider
    Elsevier, 2012
    Emneord
    Physical vapor deposition (PVD); Solid oxide fuel cell (SOFC); X-ray diffraction (XRD); Electron microscopy; Elastic recoil detection analysis (ERDA)
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-79708 (URN)10.1016/j.surfcoat.2012.04.007 (DOI)000305662400043 ()
    Tilgjengelig fra: 2012-08-13 Laget: 2012-08-13 Sist oppdatert: 2017-12-07
    2. High performance metal-supported solid oxide fuel cells with Gd-doped ceria barrier layers
    Åpne denne publikasjonen i ny fane eller vindu >>High performance metal-supported solid oxide fuel cells with Gd-doped ceria barrier layers
    Vise andre…
    2011 (engelsk)Inngår i: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 196, nr 22, s. 9459-9466Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Metal-supported solid oxide fuel cells are believed to have commercial advantages compared to conventional anode (Ni-YSZ) supported cells, with the metal-supported cells having lower material costs, increased tolerance to mechanical and thermal stresses, and lower operational temperatures. The implementation of a metallic support has been challenged by the need to revise the cell fabrication route, as well as electrode microstructures and material choices, to compete with the energy output and stability of full ceramic cells. less thanbrgreater than less thanbrgreater thanThe metal-supported SOFC design developed at Riso DTU has been improved, and an electrochemical performance beyond the state-of-the-art anode-supported SOFC is demonstrated possible, by introducing a CGO barrier layer in combination with Sr-doped lanthanum cobalt oxide (LSC) cathode. Area specific resistances (ASR) down to 0.27 Omega cm(2), corresponding to a maximum power density of 1.14 W cm(-2) at 650 degrees C and 0.6 V. were obtained on cells with barrier layers fabricated by magnetron sputtering. The performance is dependent on the density of the barrier layer, indicating Sr(2+) diffusion is occurring at the intermediate SOFC temperatures. The optimized design further demonstrate improved durability with steady degradation rates of 0.9% kh(-1) in cell voltage for up to 3000 h galvanostatic testing at 650 degrees C and 0.25 A cm(-2).

    sted, utgiver, år, opplag, sider
    Elsevier, 2011
    Emneord
    SOFC, Metal-supported, Barrier layer, Magnetron sputtering, Durability
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-71631 (URN)10.1016/j.jpowsour.2011.07.014 (DOI)000295602400048 ()
    Merknad

    Funding Agencies|Topsoe Fuel Cell A/S||Danish National Advanced Technology Foundation||EU|FP7-211940 (METSOFC)|NordForsk|9346|

    Tilgjengelig fra: 2011-10-27 Laget: 2011-10-27 Sist oppdatert: 2017-12-08
    3. Strontium diffusion in magnetron sputtered gadolinia-doped ceria thin film barrier coatings for solid oxide fuel cells
    Åpne denne publikasjonen i ny fane eller vindu >>Strontium diffusion in magnetron sputtered gadolinia-doped ceria thin film barrier coatings for solid oxide fuel cells
    Vise andre…
    2013 (engelsk)Inngår i: Advanced Energy Materials, E-ISSN 1614-6840, Vol. 3, nr 7, s. 923-929Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Strontium (Sr) diffusion in magnetron sputtered gadolinia-doped ceria (CGO) thin films is investigated. For this purpose, a model system consisting of a screen printed (La,Sr)(Co,Fe)O3−δ (LSCF) layer, and thin films of CGO and yttria-stabilized zirconia (YSZ) is prepared to simulate a solid oxide fuel cell. This setup allows observation of Sr diffusion by observing SrZrO3 formation using X-ray diffraction while annealing. Subsequent electron microscopy confirms the results. This approach presents a simple method for assessing the quality of CGO barriers without the need for a complete fuel cell test setup. CGO films with thicknesses ranging from 250 nm to 1.2 μm are tested at temperatures from 850 °C to 950 °C which yields an in-depth understanding of Sr diffusion through CGO thin films that may be of high scientific and technical interest for implementation of novel fuel cell materials. Sr is found to diffuse along column/grain boundaries in the CGO films but by modifying the film thickness and microstructure the breaking temperature of the barrier can be increased.

    sted, utgiver, år, opplag, sider
    John Wiley & Sons, 2013
    Emneord
    Ce0.9Gd0.1O2−δ; CGO; GDC; Sr diffusion; X-ray diffraction
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-84610 (URN)10.1002/aenm.201300003 (DOI)000327698200015 ()
    Merknad

    On the day of the defence date the status of this article was Manuscript.

    Tilgjengelig fra: 2012-10-15 Laget: 2012-10-15 Sist oppdatert: 2017-04-10bibliografisk kontrollert
  • 4. Bestill onlineKjøp publikasjonen >>
    Sønderby, Steffen
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Yttria-Stabilized Zirconia and Gadolinia-Doped Ceria Thin Films for Fuel Cell Applications2014Doktoravhandling, med artikler (Annet vitenskapelig)
    Abstract [en]

    Solid oxide fuel cells convert chemical energy directly into electrical energy with high efficiency and low emission of pollutants. However, before fuel cell technology can gain a significant share of the electrical power market, the operation temperature needs to be reduced in order to decrease costs and improve the durability of the cells. Application of thin film electrolytes and barrier coatings is a way of achieving this goal.

    In this thesis, I have investigated film growth and microstructure of yttria-stabilized zirconia (YSZ) and gadolinia-doped ceria (CGO) thin films deposited by physical vapor deposition. The aim is to make industrially applicable coatings suitable for application in solid oxide fuel cells (SOFCs). For this purpose, the coatings need to be thin and dense. YSZ coatings were prepared by pulsed direct current (DC) magnetron sputtering and high power impulse magnetron sputtering (HiPIMS) in both laboratory- and industrial-scale setups.

    Industrial-scale pulsed DC magnetron sputtering of YSZ showed that homogenous coating over large areas was possible. In order to increase film density of the YSZ, HiPIMS was used. By tuning deposition pressure, peak power density and substrate bias voltage it was possible to deposit noncolumnar thin films without voids and cracks as desired for SOFC applications.

    CGO coatings were deposited by pulsed DC magnetron sputtering with the purpose of implementing diffusion barriers to prevent reactions between Sr from the SOFC cathode and the electrolyte. A model system simulating a SOFC was prepared by depositing thin CGO and YSZ layers on cathode material. This setup allowed the study of Sr diffusion by observing SrZrO3 formation using X-ray diffraction while annealing. Electron microscopy was subsequently performed to confirm the results. The study revealed Sr to diffuse along column/grain boundaries in the CGO films but by modifying the film thickness and microstructure the breaking temperature of the barrier could be increased.

    CGO thin films were implemented in metal-based SOFC and the influence of film microstructure and thickness on the electrochemical performance of the cell was studied. Cell tests showed that an area specific resistance (ASR) down to 0.27 Ωcm2 could be obtained 650 °C with sputtered CGO barrier layers in combination with a lanthanum strontium cobaltite cathode. In comparison a spin-coated CGO barrier resulted in an ASR value of 0.50 Ωcm2. This shows the high effectiveness of the sputtered barrier in obtaining state-of-the-art performance.

    In summary, this work provides fundamental understanding of the deposition and growth of YSZ and CGO thins films and proves the prospective of employing thin film barrier coating in order to obtain high-performing SOFCs.  

    Delarbeid
    1. Reactive magnetron sputtering of uniform yttria-stabilized zirconia coatings in an industrial setup
    Åpne denne publikasjonen i ny fane eller vindu >>Reactive magnetron sputtering of uniform yttria-stabilized zirconia coatings in an industrial setup
    Vise andre…
    2012 (engelsk)Inngår i: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 206, nr 19-20, s. 4126-4131Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Yttria-stabilized zirconia (YSZ) thin films were deposited by reactive magnetron sputtering in an industrial scale setup on silicon wafers as well as commercial NiO-YSZ fuel cell anodes. The texture, morphology, and composition of the deposited films were investigated as a function of deposition parameters. Homogeneous coatings could be deposited over large areas within the coating zone, which is important for industrial applications. The use of substrate bias during film growth was identified as a key parameter to promote less columnar coatings and made it possible to tailor the texture of films deposited on Si. Bias voltages less than= - 40V resulted in highly less than 200 greater than textured YSZ films, intermediate bias voltages of - 50 V to - 70 V in less than 220 greater than textured films and high bias voltages (greater than= - 90 V) in a mixed orientation. In contrast, films grown on NiO-YSZ were seen to be randomly orientated when deposited at substrate bias voltages less than= - 30 V. When bias was further increased the film took over the orientation of underlying substrate due to substrate template effects.

    sted, utgiver, år, opplag, sider
    Elsevier, 2012
    Emneord
    Physical vapor deposition (PVD); Solid oxide fuel cell (SOFC); X-ray diffraction (XRD); Electron microscopy; Elastic recoil detection analysis (ERDA)
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-79708 (URN)10.1016/j.surfcoat.2012.04.007 (DOI)000305662400043 ()
    Tilgjengelig fra: 2012-08-13 Laget: 2012-08-13 Sist oppdatert: 2017-12-07
    2. Deposition of yttria-stabilized zirconia thin films by high power impulse magnetron sputtering and pulsed magnetron sputtering
    Åpne denne publikasjonen i ny fane eller vindu >>Deposition of yttria-stabilized zirconia thin films by high power impulse magnetron sputtering and pulsed magnetron sputtering
    Vise andre…
    2014 (engelsk)Inngår i: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 240, s. 1-6Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Yttria-stabilized zirconia (YSZ) thin films were reactively sputter-deposited by high power impulse magnetron sputtering (HiPIMS) and pulsed direct current magnetron sputtering (DCMS). The use of substrate bias voltage was studied in both modes of deposition as a process parameter to promote the growth of dense and less columnar films. Films were deposited on both Si(100) and NiO-YSZ fuel cell anodes. The texture, morphology and composition of the deposited films were investigated with regard to their application as thin electrolytes for solid oxide fuel cells (SOFCs). Independent of the deposition mode the films were found to be stoichiometric. The application of substrate bias voltage had opposite effects on texture and crystallinity of films deposited by pulsed DCMS and HiPIMS. Films deposited by pulsed DCMS became highly crystalline and <220> textured at high bias voltage whereas bias applied to HiPIMS deposited films disrupted crystal growth leading to deterioration of crystallinity. Comparing film morphology, it was found that pulsed DCMS films were columnar and contained voids regardless of the applied substrate bias. When depositing by HiPIMS a window of operation at a bias voltage of -25 V to -50 V was found in which it is possible to deposit non-columnar thin films without voids and cracks as desired for SOFC applications. 

    Emneord
    HiPIMS, HPPMS, pulsed DCMS, SOFC, YSZ, Substrate bias
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-102516 (URN)10.1016/j.surfcoat.2013.12.001 (DOI)000331989900001 ()
    Tilgjengelig fra: 2013-12-12 Laget: 2013-12-12 Sist oppdatert: 2017-12-06
    3. Industrial-scale high power impulse magnetron sputtering of yttria-stabilized zirconia on porous NiO/YSZ fuel cell anodes
    Åpne denne publikasjonen i ny fane eller vindu >>Industrial-scale high power impulse magnetron sputtering of yttria-stabilized zirconia on porous NiO/YSZ fuel cell anodes
    Vise andre…
    2015 (engelsk)Inngår i: SURFACE & COATINGS TECHNOLOGY, ISSN 0257-8972, Vol. 281, s. 150-156Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Yttria-stabilized zirconia (YSZ) thin films are reactively sputter-deposited by high power impulse magnetron sputtering (HiPIMS) in an industrial setup on porous NiO/YSZ fuel cell anodes. The influence of deposition pressure, peak power and substrate bias on the deposition rate and film morphology is studied. It is seen that depositing at increasing the deposition pressure from ~370 mPa to ~750 mPa results in a 64 % increase in the deposition rate and denser film. Films are deposited at peak power densities ranging from 0.4 kW/cm2 to 1.1 kW/cm2. By increasing the peak power density the degree of ionization degree of both Ar and sputtered metallic species is significantly increased which results in denser films as open column boundaries are removed. The increase in peak power also results in a significant drop in deposition rate. By combining a peak power density of ~0.6 kW/cm2 with the application of -180 V substrate bias voltage a homogenous and essentially columnless coating can be deposited. These results demonstrate HiPIMS deposition is capable of producing dense, YSZ coatings on porous substrates as needed for solid oxide fuel cell application. 

    sted, utgiver, år, opplag, sider
    Elsevier, 2015
    Emneord
    Physical Vapor deposition (PVD), Solid Oxide Fuel Cell (SOFC), YSZ, HPPMS
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-102515 (URN)10.1016/j.surfcoat.2015.09.058 (DOI)000366072200019 ()
    Tilgjengelig fra: 2013-12-12 Laget: 2013-12-12 Sist oppdatert: 2016-06-01
    4. Strontium diffusion in magnetron sputtered gadolinia-doped ceria thin film barrier coatings for solid oxide fuel cells
    Åpne denne publikasjonen i ny fane eller vindu >>Strontium diffusion in magnetron sputtered gadolinia-doped ceria thin film barrier coatings for solid oxide fuel cells
    Vise andre…
    2013 (engelsk)Inngår i: Advanced Energy Materials, E-ISSN 1614-6840, Vol. 3, nr 7, s. 923-929Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Strontium (Sr) diffusion in magnetron sputtered gadolinia-doped ceria (CGO) thin films is investigated. For this purpose, a model system consisting of a screen printed (La,Sr)(Co,Fe)O3−δ (LSCF) layer, and thin films of CGO and yttria-stabilized zirconia (YSZ) is prepared to simulate a solid oxide fuel cell. This setup allows observation of Sr diffusion by observing SrZrO3 formation using X-ray diffraction while annealing. Subsequent electron microscopy confirms the results. This approach presents a simple method for assessing the quality of CGO barriers without the need for a complete fuel cell test setup. CGO films with thicknesses ranging from 250 nm to 1.2 μm are tested at temperatures from 850 °C to 950 °C which yields an in-depth understanding of Sr diffusion through CGO thin films that may be of high scientific and technical interest for implementation of novel fuel cell materials. Sr is found to diffuse along column/grain boundaries in the CGO films but by modifying the film thickness and microstructure the breaking temperature of the barrier can be increased.

    sted, utgiver, år, opplag, sider
    John Wiley & Sons, 2013
    Emneord
    Ce0.9Gd0.1O2−δ; CGO; GDC; Sr diffusion; X-ray diffraction
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-84610 (URN)10.1002/aenm.201300003 (DOI)000327698200015 ()
    Merknad

    On the day of the defence date the status of this article was Manuscript.

    Tilgjengelig fra: 2012-10-15 Laget: 2012-10-15 Sist oppdatert: 2017-04-10bibliografisk kontrollert
    5. Magnetron sputtered Gadolina-doped Ceria Diffusion Barriers for Metal-supported Solid Oxide Fuel Cells
    Åpne denne publikasjonen i ny fane eller vindu >>Magnetron sputtered Gadolina-doped Ceria Diffusion Barriers for Metal-supported Solid Oxide Fuel Cells
    Vise andre…
    2014 (engelsk)Inngår i: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 267, s. 452-458Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Gadolinia-doped ceria (GDC) thin films are deposited by reactive magnetron sputtering in an industrial-scale setup and implemented as barrier layers between the cathode and electrolyte in metal-based solid oxide fuel cells consisting of a metal support, an electrolyte of ZrO2 co-doped with Sc2O3 and Y2O3 (ScYSZ) and a Sr-doped lanthanum cobalt oxide cathode. In order to optimize the deposition of GDC to obtain high electrochemical performance of the cells, the influence of film thickness and adatom mobility is studied. The adatom mobility is varied by tuning the deposition temperature and substrate bias voltage.

    A GDC layer thickness of 0.6 µm is found to effectively block Sr diffusion when bias voltage and deposition temperature is tuned to promote dense coatings. The adatom mobility has a large influence on the film density. Low temperature and bias voltage result in underdense column boundaries which function as channels for Sr to diffuse to the GDC-ScYSZ interface. By tuning deposition temperature, bias voltage and film thickness area specific resistances down to 0.34 Ωcm2 are achieved at cell tests performed at an operating temperature of 650 °C.

    sted, utgiver, år, opplag, sider
    Elsevier, 2014
    Emneord
    Physical Vapor deposition (PVD); Solid Oxide Fuel Cell (SOFC); GDC; CGO
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-102517 (URN)10.1016/j.jpowsour.2014.05.101 (DOI)000339601800054 ()
    Tilgjengelig fra: 2013-12-12 Laget: 2013-12-12 Sist oppdatert: 2017-12-06
    6. High performance metal-supported solid oxide fuel cells with Gd-doped ceria barrier layers
    Åpne denne publikasjonen i ny fane eller vindu >>High performance metal-supported solid oxide fuel cells with Gd-doped ceria barrier layers
    Vise andre…
    2011 (engelsk)Inngår i: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 196, nr 22, s. 9459-9466Artikkel i tidsskrift (Fagfellevurdert) Published
    Abstract [en]

    Metal-supported solid oxide fuel cells are believed to have commercial advantages compared to conventional anode (Ni-YSZ) supported cells, with the metal-supported cells having lower material costs, increased tolerance to mechanical and thermal stresses, and lower operational temperatures. The implementation of a metallic support has been challenged by the need to revise the cell fabrication route, as well as electrode microstructures and material choices, to compete with the energy output and stability of full ceramic cells. less thanbrgreater than less thanbrgreater thanThe metal-supported SOFC design developed at Riso DTU has been improved, and an electrochemical performance beyond the state-of-the-art anode-supported SOFC is demonstrated possible, by introducing a CGO barrier layer in combination with Sr-doped lanthanum cobalt oxide (LSC) cathode. Area specific resistances (ASR) down to 0.27 Omega cm(2), corresponding to a maximum power density of 1.14 W cm(-2) at 650 degrees C and 0.6 V. were obtained on cells with barrier layers fabricated by magnetron sputtering. The performance is dependent on the density of the barrier layer, indicating Sr(2+) diffusion is occurring at the intermediate SOFC temperatures. The optimized design further demonstrate improved durability with steady degradation rates of 0.9% kh(-1) in cell voltage for up to 3000 h galvanostatic testing at 650 degrees C and 0.25 A cm(-2).

    sted, utgiver, år, opplag, sider
    Elsevier, 2011
    Emneord
    SOFC, Metal-supported, Barrier layer, Magnetron sputtering, Durability
    HSV kategori
    Identifikatorer
    urn:nbn:se:liu:diva-71631 (URN)10.1016/j.jpowsour.2011.07.014 (DOI)000295602400048 ()
    Merknad

    Funding Agencies|Topsoe Fuel Cell A/S||Danish National Advanced Technology Foundation||EU|FP7-211940 (METSOFC)|NordForsk|9346|

    Tilgjengelig fra: 2011-10-27 Laget: 2011-10-27 Sist oppdatert: 2017-12-08
  • 5.
    Sønderby, Steffen
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Aijaz, Asim
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Plasma och beläggningsfysik. Linköpings universitet, Tekniska högskolan.
    Helmersson, Ulf
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Plasma och beläggningsfysik. Linköpings universitet, Tekniska högskolan.
    Sarakinos, Kostas
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Plasma och beläggningsfysik. Linköpings universitet, Tekniska högskolan.
    Eklund, Per
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Deposition of yttria-stabilized zirconia thin films by high power impulse magnetron sputtering and pulsed magnetron sputtering2014Inngår i: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 240, s. 1-6Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Yttria-stabilized zirconia (YSZ) thin films were reactively sputter-deposited by high power impulse magnetron sputtering (HiPIMS) and pulsed direct current magnetron sputtering (DCMS). The use of substrate bias voltage was studied in both modes of deposition as a process parameter to promote the growth of dense and less columnar films. Films were deposited on both Si(100) and NiO-YSZ fuel cell anodes. The texture, morphology and composition of the deposited films were investigated with regard to their application as thin electrolytes for solid oxide fuel cells (SOFCs). Independent of the deposition mode the films were found to be stoichiometric. The application of substrate bias voltage had opposite effects on texture and crystallinity of films deposited by pulsed DCMS and HiPIMS. Films deposited by pulsed DCMS became highly crystalline and <220> textured at high bias voltage whereas bias applied to HiPIMS deposited films disrupted crystal growth leading to deterioration of crystallinity. Comparing film morphology, it was found that pulsed DCMS films were columnar and contained voids regardless of the applied substrate bias. When depositing by HiPIMS a window of operation at a bias voltage of -25 V to -50 V was found in which it is possible to deposit non-columnar thin films without voids and cracks as desired for SOFC applications. 

  • 6.
    Sønderby, Steffen
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska fakulteten. Danish Technological Institute.
    Christensen, Bjarke H
    Danish Technological Institute.
    Almtoft, Klaus P.
    Danish Technological Institute.
    Nielsen, Lars P.
    Danish Technological Institute.
    Eklund, Per
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska fakulteten.
    Industrial-scale high power impulse magnetron sputtering of yttria-stabilized zirconia on porous NiO/YSZ fuel cell anodes2015Inngår i: SURFACE & COATINGS TECHNOLOGY, ISSN 0257-8972, Vol. 281, s. 150-156Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Yttria-stabilized zirconia (YSZ) thin films are reactively sputter-deposited by high power impulse magnetron sputtering (HiPIMS) in an industrial setup on porous NiO/YSZ fuel cell anodes. The influence of deposition pressure, peak power and substrate bias on the deposition rate and film morphology is studied. It is seen that depositing at increasing the deposition pressure from ~370 mPa to ~750 mPa results in a 64 % increase in the deposition rate and denser film. Films are deposited at peak power densities ranging from 0.4 kW/cm2 to 1.1 kW/cm2. By increasing the peak power density the degree of ionization degree of both Ar and sputtered metallic species is significantly increased which results in denser films as open column boundaries are removed. The increase in peak power also results in a significant drop in deposition rate. By combining a peak power density of ~0.6 kW/cm2 with the application of -180 V substrate bias voltage a homogenous and essentially columnless coating can be deposited. These results demonstrate HiPIMS deposition is capable of producing dense, YSZ coatings on porous substrates as needed for solid oxide fuel cell application. 

  • 7.
    Sønderby, Steffen
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Klemensø, Trine
    Technical University of Denmark.
    Christensen, Bjarke H.
    Danish Technological Institute.
    Almtoft, Klaus P.
    Danish Technological Institute.
    Lu, Jun
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Nielsen, Lars P.
    Danish Technological Institute.
    Eklund, Per
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Magnetron sputtered Gadolina-doped Ceria Diffusion Barriers for Metal-supported Solid Oxide Fuel Cells2014Inngår i: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 267, s. 452-458Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Gadolinia-doped ceria (GDC) thin films are deposited by reactive magnetron sputtering in an industrial-scale setup and implemented as barrier layers between the cathode and electrolyte in metal-based solid oxide fuel cells consisting of a metal support, an electrolyte of ZrO2 co-doped with Sc2O3 and Y2O3 (ScYSZ) and a Sr-doped lanthanum cobalt oxide cathode. In order to optimize the deposition of GDC to obtain high electrochemical performance of the cells, the influence of film thickness and adatom mobility is studied. The adatom mobility is varied by tuning the deposition temperature and substrate bias voltage.

    A GDC layer thickness of 0.6 µm is found to effectively block Sr diffusion when bias voltage and deposition temperature is tuned to promote dense coatings. The adatom mobility has a large influence on the film density. Low temperature and bias voltage result in underdense column boundaries which function as channels for Sr to diffuse to the GDC-ScYSZ interface. By tuning deposition temperature, bias voltage and film thickness area specific resistances down to 0.34 Ωcm2 are achieved at cell tests performed at an operating temperature of 650 °C.

  • 8.
    Sønderby, Steffen
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Lunca Popa, Petru
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Lu, Jun
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Holl Christensen, Bjarke
    Danish Technological Institute, Aarhus, Denmark.
    Pagh Almtoft, Klaus
    Danish Technological Institute, Aarhus, Denmark.
    Pleth Nielsen, Lars
    Danish Technological Institute, Aarhus, Denmark.
    Eklund, Per
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Strontium diffusion in magnetron sputtered gadolinia-doped ceria thin film barrier coatings for solid oxide fuel cells2013Inngår i: Advanced Energy Materials, E-ISSN 1614-6840, Vol. 3, nr 7, s. 923-929Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Strontium (Sr) diffusion in magnetron sputtered gadolinia-doped ceria (CGO) thin films is investigated. For this purpose, a model system consisting of a screen printed (La,Sr)(Co,Fe)O3−δ (LSCF) layer, and thin films of CGO and yttria-stabilized zirconia (YSZ) is prepared to simulate a solid oxide fuel cell. This setup allows observation of Sr diffusion by observing SrZrO3 formation using X-ray diffraction while annealing. Subsequent electron microscopy confirms the results. This approach presents a simple method for assessing the quality of CGO barriers without the need for a complete fuel cell test setup. CGO films with thicknesses ranging from 250 nm to 1.2 μm are tested at temperatures from 850 °C to 950 °C which yields an in-depth understanding of Sr diffusion through CGO thin films that may be of high scientific and technical interest for implementation of novel fuel cell materials. Sr is found to diffuse along column/grain boundaries in the CGO films but by modifying the film thickness and microstructure the breaking temperature of the barrier can be increased.

  • 9.
    Sønderby, Steffen
    et al.
    Linköpings universitet, Institutionen för fysik, kemi och biologi. Linköpings universitet, Tekniska högskolan.
    Nielsen, A. J.
    Danish Technology Institute, Denmark Aarhus University, Denmark Aarhus University, Denmark .
    Christensen, B. H.
    Danish Technology Institute, Denmark .
    Almtoft, K. P.
    Danish Technology Institute, Denmark .
    Lu, Jun
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Jensen, Jens
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Nielsen, L. P.
    Danish Technology Institute, Denmark .
    Eklund, Per
    Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska högskolan.
    Reactive magnetron sputtering of uniform yttria-stabilized zirconia coatings in an industrial setup2012Inngår i: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 206, nr 19-20, s. 4126-4131Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Yttria-stabilized zirconia (YSZ) thin films were deposited by reactive magnetron sputtering in an industrial scale setup on silicon wafers as well as commercial NiO-YSZ fuel cell anodes. The texture, morphology, and composition of the deposited films were investigated as a function of deposition parameters. Homogeneous coatings could be deposited over large areas within the coating zone, which is important for industrial applications. The use of substrate bias during film growth was identified as a key parameter to promote less columnar coatings and made it possible to tailor the texture of films deposited on Si. Bias voltages less than= - 40V resulted in highly less than 200 greater than textured YSZ films, intermediate bias voltages of - 50 V to - 70 V in less than 220 greater than textured films and high bias voltages (greater than= - 90 V) in a mixed orientation. In contrast, films grown on NiO-YSZ were seen to be randomly orientated when deposited at substrate bias voltages less than= - 30 V. When bias was further increased the film took over the orientation of underlying substrate due to substrate template effects.

1 - 9 of 9
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