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Engineering the sign of circularly polarized emission in achiral polymer - chiral small molecule blends as a function of blend ratio
Linköpings universitet, Institutionen för fysik, kemi och biologi, Elektroniska och fotoniska material. Linköpings universitet, Tekniska fakulteten. Imperial Coll London, England; Imperial Coll London, England; Imperial Coll London, England.
Imperial Coll London, England; Imperial Coll London, England; Imperial Coll London, England.
Imperial Coll London, England; Imperial Coll London, England.
Imperial Coll London, England; Imperial Coll London, England.
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2022 (engelsk)Inngår i: Journal of Materials Chemistry C, ISSN 2050-7526, E-ISSN 2050-7534, Vol. 10, nr 13, s. 5168-5172Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Circularly polarized organic light-emitting diodes (CP-OLEDs) that demonstrate both state-of-the-art efficiency and strongly circularly polarized (CP) electroluminescence have proved a considerable technical challenge. Furthermore, multiple factors - from film thickness to device structure - have been shown to influence the sign of the emitted CP light, independent of the handedness (absolute stereochemistry) of the chiral emitter. Here we report CP-OLEDs using a blend of poly(9,9-dioctylfluorene-alt-bithiophene) (F8T2) and a chiral small molecule additive (1-aza[6]helicene, aza[6]H). We demonstrate CP-OLEDs with an impressive electroluminescence dissymmetry (g(EL)) > 0.3 and a current efficiency of 0.53 cd A(-1) and brightness of 3023 cd m(-2). While at low aza[6]H loadings, F8T2 blends are consistent with previous observations of CP dissymetric inversion as a function of film thickness/excitation mode, a higher loading of aza[6]H (similar to 40 wt%) removes such dependencies while retaining excellent g-factors. The materials disclosed will allow for further mechanistic studies of chiral polymeric materials and provide new opportunities for chiroptical optimisation in films and devices.

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ROYAL SOC CHEMISTRY , 2022. Vol. 10, nr 13, s. 5168-5172
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URN: urn:nbn:se:liu:diva-183575DOI: 10.1039/d1tc05403aISI: 000764248100001OAI: oai:DiVA.org:liu-183575DiVA, id: diva2:1645480
Merknad

Funding Agencies|EPSRCUK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC) [EP/P000525/1, EP/L016702/1, EP/R00188X/1]

Tilgjengelig fra: 2022-03-17 Laget: 2022-03-17 Sist oppdatert: 2023-05-24bibliografisk kontrollert

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