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Stable DC vacuum arc plasma generation from a 100 mm TiB2 cathode
Linköpings universitet, Institutionen för fysik, kemi och biologi, Materialdesign. Linköpings universitet, Tekniska fakulteten.
Linköpings universitet, Institutionen för fysik, kemi och biologi, Materialdesign. Linköpings universitet, Tekniska fakulteten.ORCID-id: 0000-0002-9745-5380
Plansee Composite Mat GmbH, Germany.
Plansee Composite Mat GmbH, Germany.
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2024 (Engelska)Ingår i: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 484, artikel-id 130824Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Titanium diboride exhibits outstanding properties for hard and wear resistant coatings. However, efficient physical vapor deposition (PVD) processing through DC vacuum arc, with a deposition rate unreachable for any other PVD technique, is comparatively unexplored for TiB2 thin films due to challenges associated with the film synthesis process. In this work, we used an industrial scale arc plasma source having a plane cathode of 100 mm in diameter and a permanent magnet on its back side. We present analysis of the cathode surface, plasma generation/composition, as well as analysis of collected macroparticles. The cathode weight loss and the amount of generated macroparticles were measured as a function of process parameters (arc current and pressure, in both Ar and N2 gas). Plasma analysis shows average ion energies around 120 and 25 eV for Ti and B, respectively, and plasma ion composition of approximately 50 % Ti and 50 % B. The cathode weight loss was around 0.3-0.5 g/ min, of which at least 25 % is estimated to be macroparticles. Notably, the intensity of the macroparticle generation was reduced with an increase in N2 pressure. Altogether, the results show a stable and reproducible plasma generation process and a high potential for the use of the cathodic arc as an efficient and useful method for deposition of metal borides.

Ort, förlag, år, upplaga, sidor
ELSEVIER SCIENCE SA , 2024. Vol. 484, artikel-id 130824
Nyckelord [en]
TiB2; TiB2-C; Boride; DC vacuum arc; Macroparticles; Plasma diagnostics
Nationell ämneskategori
Bearbetnings-, yt- och fogningsteknik
Identifikatorer
URN: urn:nbn:se:liu:diva-204312DOI: 10.1016/j.surfcoat.2024.130824ISI: 001235696800001OAI: oai:DiVA.org:liu-204312DiVA, id: diva2:1867891
Anmärkning

Funding Agencies|Knut and Alice Wallenberg Foundation [KAW 2015.0043, J.R. 2019.0433]; Swedish Government Strategic Research Area in Materials Science on Advanced Functional Materials at Linkoping University (Faculty Grant SFO-Mat- LiU) [2009-00971]

Tillgänglig från: 2024-06-11 Skapad: 2024-06-11 Senast uppdaterad: 2024-06-11

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Zhirkov, IgorPetruhins, AndrejsRosén, Johanna
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