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Ellipsometric studies of SiC in the infrared, visual and ultraviolet spectral region
Linköping University, Department of Physics, Measurement Technology, Biology and Chemistry. Linköping University, The Institute of Technology.
2003 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Spectroscopic ellipsometry has been used to determine the dielectric function of the most common polytypes, 3C, 4H and 6H, of SiC and also of some related materials. Measurements have been performed in the infrared, visible and ultraviolet energy region. Effects such as surface roughness, crystal anisotropy, free-charge carrier concentrations, and phonon modes are discussed. For the measurements in the infrared region a Fourier transform rotating compensator ellipsometer working in the 300-8000 cm-1 wave number region has been used. The result provides an accurate determination of the dielectric function for the uniaxial structure; several phonon modes not observed with ellipsometry before but expected from Raman spectroscopy are detected. Additionally, the modeling and subsequent fitting enables determination of the effective masses and free carrier concentrations, in good agreement with result obtained by other techniques. For the visible and ultra-violet photon energy region, the results provide imminent feedback for the theoretical calculations regarding the band-to-band transitions. Measurements for energies up 9 eV have been made using a N2-purged environment and MgF optics. The results are analyzed using both real and reciprocal space analysis and critical point energies are determined.

Samples measured had free carrier concentrations in the 1017 to 1019 cm-3 range. Both single side and double side polished samples and samples with additional oxide were studied. Sample cleaning was also addressed. Additionally, some results on 3C-SiC grown on silicon are included.

Place, publisher, year, edition, pages
Linköping: Linköping University , 2003. , p. 65
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 850
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:liu:diva-179499Libris ID: 9166109ISBN: 9173737747 (print)OAI: oai:DiVA.org:liu-179499DiVA, id: diva2:1596630
Public defence
2003-11-21, hörsal Planck, Fysikhuset, Linköpings Universitet, Linköping, 10:15
Opponent
Note

All or some of the partial works included in the dissertation are not registered in DIVA and therefore not linked in this post.

Available from: 2021-09-23 Created: 2021-09-23 Last updated: 2023-03-01Bibliographically approved
List of papers
1. Optical characterization of 4H-SiC by variable angle of incidence spectroscopic ellipsometry
Open this publication in new window or tab >>Optical characterization of 4H-SiC by variable angle of incidence spectroscopic ellipsometry
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2000 (English)In: Materials Science Forum, ISSN 0255-5476, E-ISSN 1662-9752, Vol. 338-3, p. 575-578Article in journal (Refereed) Published
Abstract [en]

A variable angle of incidence spectroscopic ellipsometer equipped with a compensator has been used to determine the dielectric functions in the 0.74 - 6 eV photon energy range of n-type bulk 4H-SiC with doping concentrations between 10(17) and 10(19) cm(-3). The resulting dielectric function for different SiC wafers depends on the doping concentration, especially around the absorption onset and higher photon energies. Measurements on different wafers with the same doping show good reproducibility. Simulations and preliminary measurements show that ellipsometry might be useful for thickness determination of thin (<1 m) homoepitaxial films.

Keywords
doping concentration, ellipsometry, SiC dielectric function
National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-49439 (URN)
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2021-09-23
2. Ordinary and extraordinary dielectric functions of 4H- and 6H-SiC from 3.5 to 9.0 eV
Open this publication in new window or tab >>Ordinary and extraordinary dielectric functions of 4H- and 6H-SiC from 3.5 to 9.0 eV
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2001 (English)In: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 78, no 18, p. 2715-2717Article in journal (Refereed) Published
Abstract [en]

We report ordinary (??c axis) and extraordinary (??c axis) dielectric function data of 4H- and 6H-SiC from 3.5 to 9.0 eV. These data, which were obtained by with spectroscopic ellipsometry, are also compared to recently reported ab initio calculations. Critical point energies were found using real and reciprocal space analysis. © 2001 American Institute of Physics.

National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-47404 (URN)10.1063/1.1369617 (DOI)
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2021-09-23
3. Optical properties of 4H-SiC
Open this publication in new window or tab >>Optical properties of 4H-SiC
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2002 (English)In: Journal of Applied Physics, ISSN 0021-8979, E-ISSN 1089-7550, Vol. 91, no 3, p. 2099-2103Article in journal (Refereed) Published
Abstract [en]

The optical band gap energy and the dielectric functions of n-type 4H-SiC have been investigated experimentally by transmission spectroscopy and spectroscopic ellipsometry and theoretically by an ab initio full-potential linear muffin-tin-orbital method. We present the real and imaginary parts of the dielectric functions, resolved into the transverse and longitudinal photon moment a, and we show that the anisotropy is small in 4H-SiC. The measurements and the calculations fall closely together in a wide range of energies. © 2002 American Institute of Physics.

National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-47110 (URN)10.1063/1.1429766 (DOI)
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2021-09-23Bibliographically approved
4. Optical properties of wurtzite AlxGa1-xN (x < 0.1) parallel and perpendicular to the c axis
Open this publication in new window or tab >>Optical properties of wurtzite AlxGa1-xN (x < 0.1) parallel and perpendicular to the c axis
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2001 (English)In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, E-ISSN 1550-235X, Vol. 64, no 16Article in journal (Refereed) Published
Abstract [en]

Measurements of the dielectric function components parallel and perpendicular to the optical axis of wurtzite GaN are presented. The results are obtained on a multilayer AlxGa1-xN / GaN film grown on gamma -LiAlO2 which exhibits a very small amount of Al (x<0.1) in the uppermost layer. We use the spectroscopic ellipsometry to determine (omega) around the interband critical points of GaN up to 9 eV. Since the optical axis of the films are parallel to the surface, a separation of the different epsilon components is possible. The line shape of the measured tensor components e(parallel to) and epsilon (perpendicular to) is in very good agreement with results of recently published band-structure calculations. By comparison with the calculations we assign structures in the dielectric function to critical points in the Brillouin zone. In addition, a comparison with similar spectra for CdS and CdSe is presented, together with a discussion of possible spin-orbit splitting effects.

National Category
Natural Sciences
Identifiers
urn:nbn:se:liu:diva-49094 (URN)
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2021-09-23
5. Infrared to vacuum ultraviolet optical properties of 3C, 4H and 6H silicon carbide measured by spectroscopic ellipsometry
Open this publication in new window or tab >>Infrared to vacuum ultraviolet optical properties of 3C, 4H and 6H silicon carbide measured by spectroscopic ellipsometry
2004 (English)In: Elsevier Science, ISSN 1626-3200, Vol. 455-456, p. 235-238Article in journal (Refereed) Published
National Category
Natural Sciences
Identifiers
urn:nbn:se:liu:diva-41348 (URN)10.1016/j.tsf.2004.01.008 (DOI)55636 (Local ID)55636 (Archive number)55636 (OAI)
Available from: 2009-10-10 Created: 2009-10-10 Last updated: 2021-09-23

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Lindquist, O. P. Alexander

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