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Utilizing native lignin as redox-active material in conductive wood for electronic and energy storage applications
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering.
AlbaNova Univ Ctr, Sweden; KTH Royal Inst Technol, Sweden.
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering. RISE Res Inst Sweden Bio & Organ Elect, Sweden.
KTH Royal Inst Technol, Sweden.
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2022 (English)In: Journal of Materials Chemistry A, ISSN 2050-7488, E-ISSN 2050-7496, Vol. 10, no 29, p. 15677-15688Article in journal (Refereed) Published
Abstract [en]

Nanostructured wood veneer with added electroactive functionality combines structural and functional properties into eco-friendly, low-cost nanocomposites for electronics and energy technologies. Here, we report novel conducting polymer-impregnated wood veneer electrodes where the native lignin is preserved, but functionalized for redox activity and used as an active component. The resulting electrodes display a well-preserved structure, redox activity, and high conductivity. Wood samples were sodium sulfite-treated under neutral conditions at 165 degrees C, followed by the tailored distribution of PEDOT:PSS, not previously used for this purpose. The mild sulfite process introduces sulfonic acid groups inside the nanostructured cell wall, facilitating electrostatic interaction on a molecular level between the residual lignin and PEDOT. The electrodes exhibit a conductivity of up to 203 S m(-1) and a specific pseudo-capacitance of up to 38 mF cm(-2), with a capacitive contribution from PEDOT:PSS and a faradaic component originating from lignin. We also demonstrate an asymmetric wood pseudo-capacitor reaching a specific capacitance of 22.9 mF cm(-2) at 1.2 mA cm(-2) current density. This new wood composite design and preparation scheme will support the development of wood-based materials for use in electronics and energy storage.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2022. Vol. 10, no 29, p. 15677-15688
National Category
Other Chemistry Topics
Identifiers
URN: urn:nbn:se:liu:diva-187502DOI: 10.1039/d1ta10366kISI: 000823818600001OAI: oai:DiVA.org:liu-187502DiVA, id: diva2:1690137
Note

Funding Agencies|Wallenberg Wood Science Center (Knut and Alice Wallenberg Foundation); Karl-Erik Onnesjo Foundation; Treesearch, a collaboration platform for Swedish forest industrial research

Available from: 2022-08-25 Created: 2022-08-25 Last updated: 2023-10-24
In thesis
1. Wood Templated Organic Electronics
Open this publication in new window or tab >>Wood Templated Organic Electronics
2023 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

In today’s digital era, electronics are integral to most activities in our daily lives, offering swift and global communication, powerful data processing tools, and advanced sensor devices. However, there are drawbacks to the exponentially growing demand for electronics, such as the depletion of fossil resources, and the complexities surrounding recycling electronic waste (E-waste). As we gradually step into the era of sustainability, it is necessary to explore alternative resources and develop greener electronic technologies. For this purpose, organic electronics (OE) has emerged as an interesting alternative, owning to its potential for low-energy fabrication and use of organic materials composed of Earth-abundant elements.

The term "organic electronics" has been used widely to refer to electrical devices crafted from organic materials, typically semiconducting polymers (sCPs). This arises from the fact that most developed OE devices such as solar cells, transistors, supercapacitors, and batteries are centered around such materials. Along with the development of different semiconducting polymer varieties, materials from various natural resources have also been explored for devices’ electrodes, binders, and electrolytes. Among them, materials from the forest have emerged as abundant, renewable, and valuable options. For many years, wood has been tailored and utilized as a device template, while its components including cellulose fibrils and lignin have been widely used as structural or active components in OE. Lignin has now become an important electrode and electrolyte active material in energy storage devices.

This thesis presents new approaches and findings in the utilization of wood and lignin as active components in different OE applications. The thesis centers around two primary themes, in which the first involves the development and utilization of conductive wood (CW), containing lignin, and lignin nanoparticles (LNPs) for supercapacitors and battery applications. The second theme focuses on developing and employing conductive wood as an active electrode in the creation of a wood electrochemical transistor. Within the first theme, I have uncovered the potential of storing electricity in wood utilizing its redox-active component, native lignin. The discovery is reinforced by the successful employment of LNPs as active materials in an organic battery. Within the second theme, I have demonstrated the world's first wooden transistor, characterized its electronic performance, and discussed the pretreatment procedure of the wood substrate that is necessary for achieving a working device. This thesis is anticipated to contribute to new and valuable knowledge for encouraging the development of low-cost and sustainable OE in the future.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2023. p. 88
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 2350
Keywords
Organic electronics, Wood, Lignin, Supercapacitor, Battery, Organic electrochemical transistor (OECT)
National Category
Materials Chemistry
Identifiers
urn:nbn:se:liu:diva-198705 (URN)10.3384/9789180753654 (DOI)9789180753647 (ISBN)9789180753654 (ISBN)
Public defence
2023-11-24, K1, Kåkenhus, Campus Norrköping, Norrköping, 13:15 (English)
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Supervisors
Available from: 2023-10-24 Created: 2023-10-24 Last updated: 2023-10-24Bibliographically approved

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van Chinh, TranBelaineh Yilma, Dagmawi BelainehBerggren, MagnusEngquist, Isak
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