liu.seSearch for publications in DiVA
System disruptions
There are recurring service disruptions on some of the search portals due to high traffic. We are working to resolve the issue, you may temporarily encounter an error message.
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Doped Conjugated Polymer Enclosing a Redox Polymer: Wiring Polyquinones with Poly(3,4‐Ethylenedioxythiophene)
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0003-4221-0367
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0001-9818-1687
Show others and affiliations
2020 (English)In: Advanced Energy & Sustainability Research, E-ISSN 2699-9412, Vol. 1, no 2, article id 2000027Article in journal (Refereed) Published
Abstract [en]

The mass implementation of renewable energies is limited by the absence of efficient and affordable technology to store electrical energy. Thus, the development of new materials is needed to improve the performance of actual devices such as batteries or supercapacitors. Herein, the facile consecutive chemically oxidative polymerization of poly(1-amino-5-chloroanthraquinone) (PACA) and poly(3,4-ethylenedioxythiophene (PEDOT) resulting in a water dispersible material PACA-PEDOT is shown. The water-based slurry made of PACA-PEDOT nanoparticles can be processed as film coated in ambient atmosphere, a critical feature for scaling up the electrode manufacturing. The novel redox polymer electrode is a nanocomposite that withstands rapid charging (16 A g−1) and delivers high power (5000 W kg−1). At lower current density its storage capacity is high (198 mAh g−1) and displays improved cycling stability (60% after 5000 cycles). Its great electrochemical performance results from the combination of the redox reversibility of the quinone groups in PACA that allows a high amount of charge storage via Faradaic reactions and the high electronic conductivity of PEDOT to access to the redox-active sites. These promising results demonstrate the potential of PACA-PEDOT to make easily organic electrodes from a water-coating process, without toxic metals, and operating in non-flammable aqueous electrolyte for large scale pseudocapacitors. 

Place, publisher, year, edition, pages
John Wiley & Sons, 2020. Vol. 1, no 2, article id 2000027
Keywords [en]
chemical oxidative polymerization, energy storage, nanocomposites, redoxpolymers
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-187968DOI: 10.1002/aesr.202000027ISI: 000783017100001OAI: oai:DiVA.org:liu-187968DiVA, id: diva2:1692163
Funder
VinnovaKnut and Alice Wallenberg FoundationAvailable from: 2022-09-01 Created: 2022-09-01 Last updated: 2024-08-30Bibliographically approved

Open Access in DiVA

fulltext(4246 kB)255 downloads
File information
File name FULLTEXT01.pdfFile size 4246 kBChecksum SHA-512
ad4471cbbb213611be546d2e55557dce3ffbf325cb873a4c7b2bead19574c085cdce0cd9c61fa741e75a68a9a182974d5f5dbc1597fa1cf8c57ff5d8d8221258
Type fulltextMimetype application/pdf

Other links

Publisher's full text

Authority records

Ajjan, FátimaKhan, ZiyauddinLienemann, SamuelVagin, MikhailPetsagkourakis, IoannisGabrielsson, RogerBraun, SlawomirFahlman, MatsInganäs, OlleBerggren, MagnusCrispin, Xavier

Search in DiVA

By author/editor
Ajjan, FátimaKhan, ZiyauddinRiera-Galindo, SergiLienemann, SamuelVagin, MikhailPetsagkourakis, IoannisGabrielsson, RogerBraun, SlawomirFahlman, MatsInganäs, OlleBerggren, MagnusCrispin, Xavier
By organisation
Laboratory of Organic ElectronicsFaculty of Science & EngineeringBiomolecular and Organic Electronics
In the same journal
Advanced Energy & Sustainability Research
Materials Chemistry

Search outside of DiVA

GoogleGoogle Scholar
Total: 256 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 618 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf