liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
In Situ Lignin Sulfonation for Highly Conductive Wood/Polypyrrole Porous Composites
KTH Royal Inst Technol, Sweden; KTH Royal Inst Technol, Sweden.
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering. (Wallenberg Wood Science Center)
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0001-5365-6140
KTH Royal Inst Technol, Sweden.
Show others and affiliations
2022 (English)In: Advanced Materials Interfaces, ISSN 2196-7350, Vol. 10, no 1, article id 2201597Article in journal (Refereed) Published
Abstract [en]

To address the rising need of sustainable solutions in electronic devices, the development of electronically conductive composites based on lightweight but mechanically strong wood structures is highly desirable. Here, a facile approach for the fabrication of highly conductive wood/polypyrrole composites through top-down modification of native lignin followed by polymerization of pyrrole in wood cell wall. By sodium sulfite treatment under neutral condition, sulfonated wood veneers with increased porosity but well-preserved cell wall structure containing native lignin and lignosulfonates are obtained. The wood structure has a content of sulfonic groups up to 343 mu mol g(-1) owing to in situ sulfonated lignin which facilitates subsequent oxidative polymerization of pyrrole, achieving a weight gain of polypyrrole as high as 35 wt%. The lignosulfonates in the wood structure act as dopant and stabilizer for the synthesized polypyrrole. The composite reaches a high conductivity of 186 S m(-1) and a specific pseudocapacitance of 1.71 F cm(-2) at the current density of 8.0 mA cm(-2). These results indicate that tailoring the wood/polymer interface in the cell wall and activating the redox activity of native lignin by sulfonation are important strategies for the fabrication of porous and lightweight wood/conductive polymer composites with potential for sustainable energy applications.

Place, publisher, year, edition, pages
Wiley , 2022. Vol. 10, no 1, article id 2201597
Keywords [en]
composites; conductivity; energy; polypyrrole; sulfonated wood
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:liu:diva-189462DOI: 10.1002/admi.202201597ISI: 000865839600001OAI: oai:DiVA.org:liu-189462DiVA, id: diva2:1706039
Note

Funding Agencies|Wallenberg Wood Science Center - Knut and Alice Wallenberg Foundation

Available from: 2022-10-25 Created: 2022-10-25 Last updated: 2023-10-24Bibliographically approved
In thesis
1. Wood Templated Organic Electronics
Open this publication in new window or tab >>Wood Templated Organic Electronics
2023 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

In today’s digital era, electronics are integral to most activities in our daily lives, offering swift and global communication, powerful data processing tools, and advanced sensor devices. However, there are drawbacks to the exponentially growing demand for electronics, such as the depletion of fossil resources, and the complexities surrounding recycling electronic waste (E-waste). As we gradually step into the era of sustainability, it is necessary to explore alternative resources and develop greener electronic technologies. For this purpose, organic electronics (OE) has emerged as an interesting alternative, owning to its potential for low-energy fabrication and use of organic materials composed of Earth-abundant elements.

The term "organic electronics" has been used widely to refer to electrical devices crafted from organic materials, typically semiconducting polymers (sCPs). This arises from the fact that most developed OE devices such as solar cells, transistors, supercapacitors, and batteries are centered around such materials. Along with the development of different semiconducting polymer varieties, materials from various natural resources have also been explored for devices’ electrodes, binders, and electrolytes. Among them, materials from the forest have emerged as abundant, renewable, and valuable options. For many years, wood has been tailored and utilized as a device template, while its components including cellulose fibrils and lignin have been widely used as structural or active components in OE. Lignin has now become an important electrode and electrolyte active material in energy storage devices.

This thesis presents new approaches and findings in the utilization of wood and lignin as active components in different OE applications. The thesis centers around two primary themes, in which the first involves the development and utilization of conductive wood (CW), containing lignin, and lignin nanoparticles (LNPs) for supercapacitors and battery applications. The second theme focuses on developing and employing conductive wood as an active electrode in the creation of a wood electrochemical transistor. Within the first theme, I have uncovered the potential of storing electricity in wood utilizing its redox-active component, native lignin. The discovery is reinforced by the successful employment of LNPs as active materials in an organic battery. Within the second theme, I have demonstrated the world's first wooden transistor, characterized its electronic performance, and discussed the pretreatment procedure of the wood substrate that is necessary for achieving a working device. This thesis is anticipated to contribute to new and valuable knowledge for encouraging the development of low-cost and sustainable OE in the future.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2023. p. 88
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 2350
Keywords
Organic electronics, Wood, Lignin, Supercapacitor, Battery, Organic electrochemical transistor (OECT)
National Category
Materials Chemistry
Identifiers
urn:nbn:se:liu:diva-198705 (URN)10.3384/9789180753654 (DOI)9789180753647 (ISBN)9789180753654 (ISBN)
Public defence
2023-11-24, K1, Kåkenhus, Campus Norrköping, Norrköping, 13:15 (English)
Opponent
Supervisors
Available from: 2023-10-24 Created: 2023-10-24 Last updated: 2023-10-24Bibliographically approved

Open Access in DiVA

fulltext(4416 kB)163 downloads
File information
File name FULLTEXT01.pdfFile size 4416 kBChecksum SHA-512
04f1e47710b3d208aeda5b5cda93f4dade1251655dab829133783097e09a5b032db537b91b2b8a588e087499a44353be4b4418cb52ab464c4983f0700f7568cd
Type fulltextMimetype application/pdf

Other links

Publisher's full text

Authority records

Tran, Van ChinhEngquist, Isak

Search in DiVA

By author/editor
Tran, Van ChinhEngquist, Isak
By organisation
Laboratory of Organic ElectronicsFaculty of Science & Engineering
In the same journal
Advanced Materials Interfaces
Condensed Matter Physics

Search outside of DiVA

GoogleGoogle Scholar
Total: 163 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 162 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf