liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Electrical current modulation in wood electrochemical transistor
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering. (Wallenberg Wood Science Center)ORCID iD: 0000-0003-0122-4914
Division of Glycoscience, Department of Chemistry and Wallenberg Wood Science Center, Department of Fiber and Polymer Technology, Royal Institute of Technology, Stockholm, Sweden.ORCID iD: 0009-0007-4701-4054
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering.
Wallenberg Wood Science Center, Department of Fiber and Polymer Technology, Royal Institute of Technology, Stockholm, Sweden.ORCID iD: 0000-0003-2168-4504
Show others and affiliations
2023 (English)In: Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, E-ISSN 1091-6490, Vol. 120, no 118, article id e2218380120Article in journal (Refereed) Published
Abstract [en]

The nature of mass transport in plants has recently inspired the development of low-cost and sustainable wood-based electronics. Herein, we report a wood electrochemical transistor (WECT) where all three electrodes are fully made of conductive wood (CW). The CW is prepared using a two-step strategy of wood delignification followed by wood amalgamation with a mixed electron-ion conducting polymer, poly(3,4-ethylenedioxythiophene)–polystyrene sulfonate (PEDOT:PSS). The modified wood has an electrical conductivity of up to 69 Sm−1 induced by the formation of PEDOT:PSS microstructures inside the wood 3D scaffold. CW is then used to fabricate the WECT, which is capable of modulating an electrical current in a porous and thick transistor channel (1 mm) with an on/off ratio of 50. The device shows a good response to gate voltage modulation and exhibits dynamic switching properties similar to those of an organic electrochemical transistor. This wood-based device and the proposed working principle demonstrate the possibility to incorporate active electronic functionality into the wood, suggesting different types of bio-based electronic devices.

Place, publisher, year, edition, pages
Proceedings of the National Academy of Sciences , 2023. Vol. 120, no 118, article id e2218380120
Keywords [en]
conductivity, electrochemistry, PEDOT:PSS, transistor, wood
National Category
Polymer Chemistry Other Electrical Engineering, Electronic Engineering, Information Engineering
Identifiers
URN: urn:nbn:se:liu:diva-197080DOI: 10.1073/pnas.2218380120ISI: 001025817800003PubMedID: 37094114Scopus ID: 2-s2.0-85153687393OAI: oai:DiVA.org:liu-197080DiVA, id: diva2:1790207
Note

QC 20230713

Available from: 2023-08-22 Created: 2023-08-22 Last updated: 2024-01-10Bibliographically approved
In thesis
1. Wood Templated Organic Electronics
Open this publication in new window or tab >>Wood Templated Organic Electronics
2023 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

In today’s digital era, electronics are integral to most activities in our daily lives, offering swift and global communication, powerful data processing tools, and advanced sensor devices. However, there are drawbacks to the exponentially growing demand for electronics, such as the depletion of fossil resources, and the complexities surrounding recycling electronic waste (E-waste). As we gradually step into the era of sustainability, it is necessary to explore alternative resources and develop greener electronic technologies. For this purpose, organic electronics (OE) has emerged as an interesting alternative, owning to its potential for low-energy fabrication and use of organic materials composed of Earth-abundant elements.

The term "organic electronics" has been used widely to refer to electrical devices crafted from organic materials, typically semiconducting polymers (sCPs). This arises from the fact that most developed OE devices such as solar cells, transistors, supercapacitors, and batteries are centered around such materials. Along with the development of different semiconducting polymer varieties, materials from various natural resources have also been explored for devices’ electrodes, binders, and electrolytes. Among them, materials from the forest have emerged as abundant, renewable, and valuable options. For many years, wood has been tailored and utilized as a device template, while its components including cellulose fibrils and lignin have been widely used as structural or active components in OE. Lignin has now become an important electrode and electrolyte active material in energy storage devices.

This thesis presents new approaches and findings in the utilization of wood and lignin as active components in different OE applications. The thesis centers around two primary themes, in which the first involves the development and utilization of conductive wood (CW), containing lignin, and lignin nanoparticles (LNPs) for supercapacitors and battery applications. The second theme focuses on developing and employing conductive wood as an active electrode in the creation of a wood electrochemical transistor. Within the first theme, I have uncovered the potential of storing electricity in wood utilizing its redox-active component, native lignin. The discovery is reinforced by the successful employment of LNPs as active materials in an organic battery. Within the second theme, I have demonstrated the world's first wooden transistor, characterized its electronic performance, and discussed the pretreatment procedure of the wood substrate that is necessary for achieving a working device. This thesis is anticipated to contribute to new and valuable knowledge for encouraging the development of low-cost and sustainable OE in the future.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2023. p. 88
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 2350
Keywords
Organic electronics, Wood, Lignin, Supercapacitor, Battery, Organic electrochemical transistor (OECT)
National Category
Materials Chemistry
Identifiers
urn:nbn:se:liu:diva-198705 (URN)10.3384/9789180753654 (DOI)9789180753647 (ISBN)9789180753654 (ISBN)
Public defence
2023-11-24, K1, Kåkenhus, Campus Norrköping, Norrköping, 13:15 (English)
Opponent
Supervisors
Available from: 2023-10-24 Created: 2023-10-24 Last updated: 2024-01-10Bibliographically approved

Open Access in DiVA

fulltext(4200 kB)92 downloads
File information
File name FULLTEXT01.pdfFile size 4200 kBChecksum SHA-512
72126f913652dfa44a945f5f63a400755e14b7d7a54bc5030d14b838bab5a1c2d96ecbe2e02152d08a99b965b7224b0fa09c762e67381aeb2b17443923f01132
Type fulltextMimetype application/pdf

Other links

Publisher's full textPubMedScopus

Authority records

Tran, Van ChinhMastantuoni, Gabriella G.Li, LengwanBerglund, LarsBerggren, MagnusZhou, QiEngquist, Isak

Search in DiVA

By author/editor
Tran, Van ChinhMastantuoni, Gabriella G.Zabihipour, MarziehLi, LengwanBerglund, LarsBerggren, MagnusZhou, QiEngquist, Isak
By organisation
Laboratory of Organic ElectronicsFaculty of Science & Engineering
In the same journal
Proceedings of the National Academy of Sciences of the United States of America
Polymer ChemistryOther Electrical Engineering, Electronic Engineering, Information Engineering

Search outside of DiVA

GoogleGoogle Scholar
Total: 92 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 215 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf