Large mechanical properties enhancement in ceramics through vacancy-mediated unit cell disturbanceShow others and affiliations
2023 (English)In: Nature Communications, E-ISSN 2041-1723, Vol. 14, no 1, article id 8387Article in journal (Refereed) Published
Abstract [en]
Tailoring vacancies is a feasible way to improve the mechanical properties of ceramics. However, high concentrations of vacancies usually compromise the strength (or hardness). We show that a high elasticity and flexural strength could be achieved simultaneously using a nitride superlattice architecture with disordered anion vacancies up to 50%. Enhanced mechanical properties primarily result from a distinctive deformation mechanism in superlattice ceramics, i.e., unit-cell disturbances. Such a disturbance substantially relieves local high-stress concentration, thus enhancing deformability. No dislocation activity involved also rationalizes its high strength. The work renders a unique understanding of the deformation and strengthening/toughening mechanism in nitride ceramics.
Place, publisher, year, edition, pages
Nature Publishing Group, 2023. Vol. 14, no 1, article id 8387
National Category
Physical Sciences
Identifiers
URN: urn:nbn:se:liu:diva-201116DOI: 10.1038/s41467-023-44060-xISI: 001130352200011PubMedID: 38104109Scopus ID: 2-s2.0-85179936308OAI: oai:DiVA.org:liu-201116DiVA, id: diva2:1839790
Note
Funding: Austrian Science Fund (Fonds zur Frderung der Wissenschaftlichen Forschung) [FWF P 33696]; China Scholarship Council (CSC) [201908440933]; Competence Center Functional Nanoscale Materials (FunMat-II) (Vinnova) [2022-03071]; Swedish Research Council (VR) [Ndegrees VR-2021-04426]; Swedish Research Council [Ndegrees VR-2015-04630]
2024-02-222024-02-222024-12-05Bibliographically approved