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Large mechanical properties enhancement in ceramics through vacancy-mediated unit cell disturbance
Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Leoben, Austria.
Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Leoben, Austria.
Linköping University, Department of Physics, Chemistry and Biology, Theoretical Physics. Linköping University, Faculty of Science & Engineering. Institute of Materials Science and Technology, TU Wien, A-1060, Vienna, Austria.ORCID iD: 0000-0001-7901-4736
Institute of Materials Science and Technology, TU Wien, Vienna, Austria.
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2023 (English)In: Nature Communications, E-ISSN 2041-1723, Vol. 14, no 1, article id 8387Article in journal (Refereed) Published
Abstract [en]

Tailoring vacancies is a feasible way to improve the mechanical properties of ceramics. However, high concentrations of vacancies usually compromise the strength (or hardness). We show that a high elasticity and flexural strength could be achieved simultaneously using a nitride superlattice architecture with disordered anion vacancies up to 50%. Enhanced mechanical properties primarily result from a distinctive deformation mechanism in superlattice ceramics, i.e., unit-cell disturbances. Such a disturbance substantially relieves local high-stress concentration, thus enhancing deformability. No dislocation activity involved also rationalizes its high strength. The work renders a unique understanding of the deformation and strengthening/toughening mechanism in nitride ceramics.

Place, publisher, year, edition, pages
Nature Publishing Group, 2023. Vol. 14, no 1, article id 8387
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Physical Sciences
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URN: urn:nbn:se:liu:diva-201116DOI: 10.1038/s41467-023-44060-xISI: 001130352200011PubMedID: 38104109Scopus ID: 2-s2.0-85179936308OAI: oai:DiVA.org:liu-201116DiVA, id: diva2:1839790
Note

Funding: Austrian Science Fund (Fonds zur Frderung der Wissenschaftlichen Forschung) [FWF P 33696]; China Scholarship Council (CSC) [201908440933]; Competence Center Functional Nanoscale Materials (FunMat-II) (Vinnova) [2022-03071]; Swedish Research Council (VR) [Ndegrees VR-2021-04426]; Swedish Research Council [Ndegrees VR-2015-04630]

Available from: 2024-02-22 Created: 2024-02-22 Last updated: 2024-12-05Bibliographically approved

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Koutná, NikolaSangiovanni, Davide Giuseppe

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