liu.seSearch for publications in DiVA
System disruptions
There are recurring service disruptions on some of the search portals due to high traffic. We are working to resolve the issue, you may temporarily encounter an error message.
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Catalysts for 2e– Oxygen Reduction Reaction: Applications in Sustainable Photochemical and Electrochemical Systems
Linköping University, Department of Science and Technology, Laboratory of Organic Electronics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0009-0005-9200-9970
2026 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

The oxygen reduction reaction (ORR) proceeds via two or four electron pathways, yielding hydrogen peroxide (H2O2) or water, respectively, and is central to energy and environmental technologies. This thesis investigates organic-material/composite catalysts that selectively promote the two-electron ORR in aqueous and alkaline media, and demonstrates their application in photochemical H2O2 generation and electrochemical H2O2 electro-synthesis and energy storage.

The first part presents a scalable, cellulose-based photoactive material: ZnO nanowires grown on paper-like cellulose substrates inspired by papermaking. The resulting ZnO–cellulose “photoactive wallpaper” drives photo-catalytic 2e- ORR under light to produce H2O2, offering a low-energy route for in situ disinfection and pollutant degradation, with clear potential for decentralized environmental remediation.

The second part focuses on the conducting polymer PEDOT (particularly PEDOT:PSS) as an electrocatalyst and ionic conductor for 2e- ORR. We systematically study the roles of primary dopants and secondary (processing) dopants on conductivity, heterogeneous electron transfer, capacitance, and apparent diffusion through the polymer. Secondary doping enhances electrochemically active surface area and mass transport, enabling efficient gas-diffusion electrodes (GDEs) for H2O2 production directly from air. Leveraging PEDOT:PSS’s combined electronic and ionic transport, 3D PEDOT:PSS cathodes enable H2O2 electrosynthesis in pure water, reaching 6.6 mg h-1 cm-2 production at 70% Faradaic efficiency and low energy consumption.

Finally, applying PEDOT:PSS as an air cathode in rechargeable zinc–air batteries (ZAB) demonstrates improved reversibility and kinetics compared with conventional carbon cathodes; a PEDOT:PSS-based ZAB in a near-neutral water-in-salt electrolyte exhibits >70% round-trip efficiency and stable cycling. Together, these studies identify organic catalysts—both electro-catalytic and photocatalytic—that selectively promote 2e- ORR and demonstrate their utility in sustainable, decentralized chemical and energy technologies.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2026. , p. 87
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 2548
Keywords [en]
Oxygen reduction reaction (ORR), Hydrogen peroxide (H2O2), Conducting polymer, secondary doping
National Category
Materials Chemistry Physical Chemistry Catalytic Processes
Identifiers
URN: urn:nbn:se:liu:diva-227688DOI: 10.3384/9789181187076ISBN: 9789181187083 (print)ISBN: 9789181187076 (electronic)OAI: oai:DiVA.org:liu-227688DiVA, id: diva2:2101840
Public defence
2026-10-14, K1, Kåkenhus, Campus Norrköping, Norrköping, 10:15 (English)
Opponent
Supervisors
Note

2026-09-16: URL (DOI) has been corrected in the E-version. 

2026-09-22: The PDF-file was replaced due to an incorrect title page and back cover. The PDF file had been downloaded 10 times before it was replaced.

Available from: 2026-09-16 Created: 2026-09-16 Last updated: 2026-09-22Bibliographically approved
List of papers
1. Toward Photoactive Wallpapers Based on ZnO-Cellulose Nanocomposites
Open this publication in new window or tab >>Toward Photoactive Wallpapers Based on ZnO-Cellulose Nanocomposites
Show others...
2023 (English)In: Global Challenges, E-ISSN 2056-6646, Vol. 7, article id 2300034Article in journal (Refereed) Published
Abstract [en]

The quest for eco-friendly materials with anticipated positive impact for sustainability is crucial to achieve the UN sustainable development goals. Classical strategies of composite materials can be applied on novel nanomaterials and green materials. Besides the actual technology and applications also processing and manufacturing methods should be further advanced to make entire technology concepts sustainable. Here, they show an efficient way to combine two low-cost materials, cellulose and zinc oxide (ZnO), to achieve novel functional and "green" materials via paper-making processes. While cellulose is the most abundant and cost-effective organic material extractable from nature. ZnO is cheap and known of its photocatalytic, antibacterial, and UV absorption properties. ZnO nanowires are grown directly onto cellulose fibers in water solutions and then dewatered in a process mimicking existing steps of large-scale papermaking technology. The ZnO NW paper exhibits excellent photo-conducting properties under simulated sunlight with good ON/OFF switching and long-term stability (90 minutes). It also acts as an efficient photocatalyst for hydrogen peroxide (H2O2) generation (5.7 x 10(-9) m s(-1)) with an envision the possibility of using it in buildings to enable large surfaces to spontaneously produce H2O2 at its outer surface. Such technology promise for fast degradation of microorganisms to suppress the spreading of diseases.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH, 2023
Keywords
anti-microorganism wallpapers; cellulose pulp fiber; large-scale fabrication; photocatalytic and photoconductive; ZnO nanowires
National Category
Composite Science and Engineering
Identifiers
urn:nbn:se:liu:diva-197877 (URN)10.1002/gch2.202300034 (DOI)001680605600001 ()37745827 (PubMedID)2-s2.0-85168975339 (Scopus ID)
Note

Funding Agencies|Knut and Alice Wallenberg Foundation; VINNOVA (Digital Cellulose Center); Vetenskapradet [2016-05990]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoeping University [2009-00971]; aForsk Foundation [17-433]

Available from: 2023-09-19 Created: 2023-09-19 Last updated: 2026-09-28
2. Decoupling Conductivity, Heterogeneous Electron Transfer Rate, and Diffusion in Organic Molecular Electrocatalysis: Oxygen Reduction Reaction on Poly(3,4-ethylenedioxythiophene)
Open this publication in new window or tab >>Decoupling Conductivity, Heterogeneous Electron Transfer Rate, and Diffusion in Organic Molecular Electrocatalysis: Oxygen Reduction Reaction on Poly(3,4-ethylenedioxythiophene)
Show others...
2025 (English)In: Small, ISSN 1613-6810, E-ISSN 1613-6829, Vol. 21, no 5, article id 2409471Article in journal (Refereed) Published
Abstract [en]

The electrified production of hydrogen peroxide (H2O2) by oxygen reduction reaction (ORR) is attractive to increase the sustainability of chemical industry. Here the same chains of intrinsically conductive polymer, poly(3,4-ethylenedioxythiophene) (PEDOT) are utilized, as ORR electrocatalyst, while varying polymeric primary dopants (PSS and Nafion) and the level of secondary doping with DMSO. These changes modulate various properties of the film, such as its microscale organization and electronic conductivity. The aim here is to clearly decouple the rate of the heterogeneous electron transfer (HET) of ORR from the diffusion affected by electronic conductivity and the electrochemically available surface area. It is found that the rate of HET and the double layer capacitance are significantly affected by primary dopant. On the contrary, secondary doping shows very little effect on the rate of HET. However, such secondary doping resulted in the increase of both electrochemically available surface area and the diffusion through the polymer film. This effect is attributed to a few orders increase of the electronic conductivity in the film improving availability of the polymer for electron transfer. The enhancement of diffusion upon the secondary doping of conducting polymer is utilized to improve direct conversion of air into H2O2 on gas diffusion electrode.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH, 2025
Keywords
4-ethylenedioxythiophene); nafion; oxygen reduction reaction; poly(3, poly(styrenesulfonate); secondary doping
National Category
Materials Chemistry
Identifiers
urn:nbn:se:liu:diva-210715 (URN)10.1002/smll.202409471 (DOI)001377464100001 ()39676389 (PubMedID)2-s2.0-85212110448 (Scopus ID)
Note

Funding Agencies|VINNOVA (Digital Cellulose Center); Knut and Alice Wallenberg foundation [KAW 2019.0604]; Wallenberg Wood Science Center (WWSC); Wallenberg Initiative Materials Science for Sustainability (WISE), KAW Project [2018]; Swedish Energy Agency [52023-1]; Vetenskapsradet [2016-05990]; Research Council of Finland [320165]; Finnish Center of Excellence program on Life-Inspired Materials LIBER [346107]; Finnish Flagship program on Photonics Research and Innovation PREIN [320165]; EU H2020 Marie Sklodowska-Curie [101022777]; [KAW 2021.0195]; [2019-05577]

Available from: 2025-01-10 Created: 2025-01-10 Last updated: 2026-09-16

Open Access in DiVA

fulltext(24298 kB)33 downloads
File information
File name FULLTEXT03.pdfFile size 24298 kBChecksum SHA-512
52067dd4f4ff5c2e2ad14813f81636ec4409e1e27b4d704a7b0c4b7cb0de7a20c51c474b33bd777dab5512f1e7988159d583478d2dbaaa3afd76dffe42e1ebed
Type fulltextMimetype application/pdf
Order online >>

Other links

Publisher's full text

Authority records

Sepat, Neha

Search in DiVA

By author/editor
Sepat, Neha
By organisation
Laboratory of Organic ElectronicsFaculty of Science & Engineering
Materials ChemistryPhysical ChemistryCatalytic Processes

Search outside of DiVA

GoogleGoogle Scholar
Total: 52 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
isbn
urn-nbn

Altmetric score

doi
isbn
urn-nbn
Total: 252 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf