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Double Active Layers Constructed with Halide Perovskite and Quantum Dots for Broadband Photodetection
Univ Sci and Technol, Peoples R China.
Linköping University, Department of Physics, Chemistry and Biology, Biomolecular and Organic Electronics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Biomolecular and Organic Electronics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0002-2582-1740
Univ Sci and Technol, Peoples R China.
2020 (English)In: Advanced Optical Materials, ISSN 2162-7568, E-ISSN 2195-1071, Vol. 8, no 17, article id 2000557Article in journal (Refereed) Published
Abstract [en]

Herein, solution-processed, high-performance broadband (300-1100 nm) photodetectors based on double active layers incorporating narrow-bandgap CuInSe2 (CISe) quantum dots (QDs) and halide perovskite are devised. The CISe QDs/perovskite film as the photoactive layer boosts the photocurrent and suppresses dark current. Due to the joint light absorption effect of CISe QDs and halide perovskite, the photoelectric conversion capacity is improved. Furthermore, CISe QDs as an electron-blocking layer can effectively block electrons to the hole transport layer and reduce the thermal noise. The optimized photodetector exhibits responsivity over 150 mA W-1 in the visible and more than 20 mA W-1 in the near-infrared (800-1000 nm) ranges, specific detectivity of more than 7.0 x 10(12) Jones in the visible region and 7.7 x 10(11) Jones in the near-infrared region, a transient response time of 277 ns with the active area of 0.013 cm(2), and a linear dynamic range of approximate to 75 dB. Importantly, the CISe QDs layer makes the perovskite denser and more hydrophobic, thus improves the environmental and thermal stability of the detector, even extends the working temperature to exceeding 150 degrees C. The design concept and the considerable performance of this novel device provide a reference value for polychromatic light detection.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2020. Vol. 8, no 17, article id 2000557
Keywords [en]
broadband photodetectors; CuInSe2 quantum dots; double active layers; perovskites; thermal stability
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Identifiers
URN: urn:nbn:se:liu:diva-166155DOI: 10.1002/adom.202000557ISI: 000535236500001OAI: oai:DiVA.org:liu-166155DiVA, id: diva2:1437761
Note

Funding Agencies|National Natural Science Foundation of ChinaNational Natural Science Foundation of China [51961135107, 51774034, 51772026]; National Key R&D Program of China [2017YFE0119700]; Beijing Natural Science FoundationBeijing Natural Science Foundation [2182039]

Available from: 2020-06-09 Created: 2020-06-09 Last updated: 2022-10-24

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