Synthesis of Two-Dimensional Metal-Organic Frameworks via Dehydrogenation Reactions on a Cu(111) SurfaceShow others and affiliations
2020 (English)In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 124, no 23, p. 12390-12396Article in journal (Refereed) Published
Abstract [en]
Metal-organic frameworks prepared on surfaces (SMOFs) have been considered to have potential applications in various research fields. Traditionally, the SMOFs are prepared by coadsorbing organic ligands and metal atoms on surfaces. In this article, we successfully construct the SMOFs via the dehydrogenation reactions of aromatic amines on the Cu(111) surfaces. The dehydrogenated nitrogen radicals interact with the copper adatoms, forming the N-Cu-N bonds. Combining with the scanning tunneling microscopy and the density functional theory calculations, we obtain the structural models of the SMOFs.
Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2020. Vol. 124, no 23, p. 12390-12396
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-167671DOI: 10.1021/acs.jpcc.0c00931ISI: 000541745800023OAI: oai:DiVA.org:liu-167671DiVA, id: diva2:1454722
Note
Funding Agencies|Collaborative Innovation Center of Suzhou Nano Science Technology; Priority Academic Program Development of Jiangsu Higher Education Institutions; National Major State Basic Research Development Program of ChinaNational Basic Research Program of China [2017YFA0205000]; National Science Foundation of ChinaNational Natural Science Foundation of China [21622306, 21872099, 51821002, 21790053]
2020-07-202020-07-202020-07-20