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Thermal degradation of TiN and TiAlN coatings during rapid laser treatment
Linköping University, Faculty of Science & Engineering. Linköping University, Department of Physics, Chemistry and Biology, Nanostructured Materials.
Linköping University, Department of Physics, Chemistry and Biology, Nanostructured Materials. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0002-0866-1909
SECO Tools AB, Sweden.
Linköping University, Department of Physics, Chemistry and Biology, Thin Film Physics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0002-8469-5983
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2021 (English)In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 422, article id 127517Article in journal (Refereed) Published
Abstract [en]

In this research, a fundamental study was conducted on damage behavior of cathodic arc evaporated TiN and Ti0.44Al0.56N coatings, in terms of oxidation and cracking/spallation, when they were exposed to single-pulse laser treatment in a temperature range of 1200-2100 degrees C. Moreover, a multiple-pulse laser treatment was designed to apply thermo-mechanical loads on the coatings in order to evaluate their thermal degradation during rapid heating/cooling cycles between 200 and 1200 degrees C. Single-pulse treatment of TiN up to 1500 degrees C led to the intercolumnar cracking and formation of ultrafine TiO grains. An increase in temperature up to 2100 degrees C resulted in a notable bulging of the surface, and formation of TiO2 of various morphologies such as grainy structure, dense molten and re-solidified structure, droplets from melt expulsion and, more interestingly, nanofibers. Multiplepulse treatment of TiN was accompanied by a severe cracking and spallation, which divided the surface into two layers: a heavily cracked top layer composed of dense TiO2 grains, and a bottom layer having porous TiO2 grains indicating incomplete oxidation. Conversely, Ti0.44Al0.56N did not show any visible cracking and oxidation after single-pulse treatment. Multiple-pulse treatment did not also yield cracking and spallation for Ti0.44Al0.56N, and its ablated region consisted of TiO2 grains combined with thin Al2O3 platelets. An excellent combination of properties including higher oxidation resistance and greater fracture toughness at high temperatures led to a higher thermal damage resistance for Ti0.44Al0.56N coating compared to TiN when undergoing single- and multiple-pulse laser treatments.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE SA , 2021. Vol. 422, article id 127517
Keywords [en]
Nitride coatings; Laser treatment; Thermal degradation; Electron microscopy
National Category
Manufacturing, Surface and Joining Technology
Identifiers
URN: urn:nbn:se:liu:diva-178742DOI: 10.1016/j.surfcoat.2021.127517ISI: 000685607200041OAI: oai:DiVA.org:liu-178742DiVA, id: diva2:1589393
Note

Funding Agencies|VINNOVAVinnova [2016-05156]; Swedish Research CouncilSwedish Research CouncilEuropean Commission [2017-06701]; Swedish government strategic research area grant AFM -SFO MatLiU [2009-00971]

Available from: 2021-08-31 Created: 2021-08-31 Last updated: 2025-06-03

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Jafari, MajidRogström, LinaBirch, JensJoesaar, Mats J.Odén, Magnus
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