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Numerical Investigation of the Stimulated Growth of Single-Crystal Fibers by Point-Effect-Induced Fluid Dynamics
Shandong Univ, Peoples R China.
Shandong Univ, Peoples R China.
Soochow Univ, Peoples R China.
Shandong Univ, Peoples R China.
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2022 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 22, no 12, p. 7031-7039Article in journal (Refereed) Published
Abstract [en]

Using molecular dynamics analysis and a two-component diffusion model that accounts for the time-dependent crystal surface chemical reaction, we show by extensive numerical simulations that the recently observed prismatic facet growth suppression in single-crystal fibers is the combined action of self-shielding by crystal surface selectivity and self-channeling arising from a point effect due to fibers small diameters and large aspect ratios. We further show that the self-channeling leads to a pyramidal-face-aiming solute flow, resulting in accelerated single-crystal fiber growth. This mesoscopic stimulated matter growth acceleration theory can satisfactorily explain all experimental results reported to date. This new crystal fiber growth technology opens a realm of application possibilities for single-crystal fiber architectures in chip-size photonics.

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2022. Vol. 22, no 12, p. 7031-7039
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-190213DOI: 10.1021/acs.cgd.2c00690ISI: 000883665400001OAI: oai:DiVA.org:liu-190213DiVA, id: diva2:1714580
Note

Funding Agencies|Natural Science Foundation of Shandong Province; Fundamental Research Funds of Shandong University; National Natural Science Foundation of China; Primary Research & Development Plan of Shandong Province; [61975154]; [2017CXGC0413]

Available from: 2022-11-30 Created: 2022-11-30 Last updated: 2023-11-07Bibliographically approved

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Durbeej, Bo

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