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Air-stable ternary organic solar cells achieved by using fullerene additives in non-fullerene acceptor-polymer donor blends
Northwestern Univ, IL 60208 USA; Univ Palermo, Italy; Univ Palermo, Italy.
Univ Palermo, Italy.
Northwestern Univ, IL 60208 USA.
Northwestern Univ, IL 60208 USA; Chinese Acad Sci, Peoples R China.
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2023 (English)In: Journal of Materials Chemistry C, ISSN 2050-7526, E-ISSN 2050-7534, Vol. 11, no 24, p. 8074-8083Article in journal (Refereed) Published
Abstract [en]

Organic solar cells (OSCs) based on donor-acceptor blends have shown a rapid improvement in power conversion efficiency (PCE) now approaching, for small cells, those of the state-of-the art commercial solar modules. However, performance degradation remains one of the most critical impediments for OSC technology commercialization. Ternary solar cells where a third component, for instance an acceptor, is added to a non-fullerene acceptor-polymer donor blend are an effective approach for improving both OSC efficiency and long-term stability. Here, we study the role of two fullerene acceptors, ET18 and PCBM, as the third component in P-D:Y6 blends. These fullerene derivatives significantly enhance the cell stability, which retained > 90% of their initial PCEs (13-14%) even after storage in air for 6 months, compared to only similar to 20% retention for the binary devices. GIWAXS, AFM, in situ impedance spectroscopy and femtosecond transient absorption spectroscopy measurements reveal that the enhanced stability of the ternary devices results from a more robust blend morphology reducing charge recombination in the ternary devices during aging.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2023. Vol. 11, no 24, p. 8074-8083
National Category
Polymer Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-192504DOI: 10.1039/d2tc04971fISI: 000940808700001OAI: oai:DiVA.org:liu-192504DiVA, id: diva2:1745021
Note

Funding Agencies|Northwestern University MRSEC (NSF) [DMR-1720139]; AFOSR [FA9550-18-1-0320, 70NANB19H005]; U.S. Department of Commerce, National Institute of Standards and Technology as part of the Center for Hierarchical Materials Design; Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF) [ECCS-1542205]; Department of Energy; DOE Office of Science by Argonne National Laboratory [DE-AC02-06CH11357]; National Science Foundation Materials Research Science and Engineering Center (MRSEC) at Northwestern University [DE-FG02-99ER14999]; U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [ARS01_00334]; University of Palermo acknowledges the Ministry of University and Research (MUR) and its program PON RI [22209169]; National Natural Science Foundation of China

Available from: 2023-03-21 Created: 2023-03-21 Last updated: 2024-03-18Bibliographically approved

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Facchetti, Antonio
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Laboratory of Organic ElectronicsFaculty of Science & Engineering
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