Sub-30 nm 2D Perovskites Patterns via Block Copolymer Guided Self-Assembly for Color Conversion Optical PolarizerShow others and affiliations
2023 (English)In: Small, ISSN 1613-6810, E-ISSN 1613-6829, Vol. 19, no 47, article id 2300568Article in journal (Refereed) Published
Abstract [en]
Despite the remarkable advances made in the development of 2D perovskites suitable for various high-performance devices, the development of sub-30 nm nanopatterns of 2D perovskites with anisotropic photoelectronic properties remains challenging. Herein, a simple but robust route for fabricating sub-30 nm 1D nanopatterns of 2D perovskites over a large area is presented. This method is based on nanoimprinting a thin precursor film of a 2D perovskite with a topographically pre-patterned hard poly(dimethylsiloxane) mold replicated from a block copolymer nanopattern consisting of guided self-assembled monolayered in-plane cylinders. 1D nanopatterns of various 2D perovskites (A & PRIME;(2)MA(n)(-1)Pb(n)X(3)(n)(+1),A & PRIME; = BA, PEA, X = Br, I) are developed; their enhanced photoluminescence (PL) quantum yields are approximately four times greater than those of the corresponding control flat films. Anisotropic photocurrent is observed because 2D perovskite nanocrystals are embedded in a topological 1D nanopattern. Furthermore, this 1D metal-coated nanopattern of a 2D perovskite is employed as a color conversion optical polarizer, in which polarized PL is developed. This is due to its capability of polarization of an incident light arising from the sub-30 nm line pattern, as well as the PL of the confined 2D perovskite nanocrystals in the pattern.
Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2023. Vol. 19, no 47, article id 2300568
Keywords [en]
anisotropic photodetection; block copolymer guided self-assembly; nanoimprinting; photoluminescent optical polarizers; sub-30 nm nanopattern of 2D perovskites
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:liu:diva-197501DOI: 10.1002/smll.202300568ISI: 001039246600001PubMedID: 37518679OAI: oai:DiVA.org:liu-197501DiVA, id: diva2:1795701
Note
Funding Agencies|National Research Foundation (NRF) - Ministry of Science and ICT [2022R1F1A1076251]; National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2018M3D1A1058536]; National Research Foundation of Korea (NRF) - Korean government (MEST) [2020R1A2B5B03002697]; National Research Foundation of Korea - Ministry of Science, ICT and Future Planning [2022M3C1A3081211]; Open Resource Research Program of the Korea Institute of Science and Technology [2E31551]; National Research Foundation of Korea [2022R1F1A1076251, 2022M3C1A3081211] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
2023-09-112023-09-112024-10-10Bibliographically approved