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Stable DC vacuum arc plasma generation from a 100 mm TiB2 cathode
Linköping University, Department of Physics, Chemistry and Biology, Materials design. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Materials design. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0002-9745-5380
Plansee Composite Mat GmbH, Germany.
Plansee Composite Mat GmbH, Germany.
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2024 (English)In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 484, article id 130824Article in journal (Refereed) Published
Abstract [en]

Titanium diboride exhibits outstanding properties for hard and wear resistant coatings. However, efficient physical vapor deposition (PVD) processing through DC vacuum arc, with a deposition rate unreachable for any other PVD technique, is comparatively unexplored for TiB2 thin films due to challenges associated with the film synthesis process. In this work, we used an industrial scale arc plasma source having a plane cathode of 100 mm in diameter and a permanent magnet on its back side. We present analysis of the cathode surface, plasma generation/composition, as well as analysis of collected macroparticles. The cathode weight loss and the amount of generated macroparticles were measured as a function of process parameters (arc current and pressure, in both Ar and N2 gas). Plasma analysis shows average ion energies around 120 and 25 eV for Ti and B, respectively, and plasma ion composition of approximately 50 % Ti and 50 % B. The cathode weight loss was around 0.3-0.5 g/ min, of which at least 25 % is estimated to be macroparticles. Notably, the intensity of the macroparticle generation was reduced with an increase in N2 pressure. Altogether, the results show a stable and reproducible plasma generation process and a high potential for the use of the cathodic arc as an efficient and useful method for deposition of metal borides.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE SA , 2024. Vol. 484, article id 130824
Keywords [en]
TiB2; TiB2-C; Boride; DC vacuum arc; Macroparticles; Plasma diagnostics
National Category
Manufacturing, Surface and Joining Technology
Identifiers
URN: urn:nbn:se:liu:diva-204312DOI: 10.1016/j.surfcoat.2024.130824ISI: 001235696800001OAI: oai:DiVA.org:liu-204312DiVA, id: diva2:1867891
Note

Funding Agencies|Knut and Alice Wallenberg Foundation [KAW 2015.0043, J.R. 2019.0433]; Swedish Government Strategic Research Area in Materials Science on Advanced Functional Materials at Linkoping University (Faculty Grant SFO-Mat- LiU) [2009-00971]

Available from: 2024-06-11 Created: 2024-06-11 Last updated: 2024-06-11

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