Utilizing satellite imagery for wildfire detection presents substantial potential for practical applications. To advance the development of machine learning algorithms in this domain, our study introduces the Sen2Fire dataset-a challenging satellite remote sensing dataset tailored for wildfire detection. This dataset is curated from Sentinel-2 multi-spectral data and Sentinel-5P aerosol product, comprising a total of 2466 image patches. Each patch has a size of 512x512 pixels with 13 bands. Given the distinctive sensitivities of various wavebands to wildfire responses, our research focuses on optimizing wildfire detection by evaluating different wavebands and employing a combination of spectral indices, such as normalized burn ratio (NBR) and normalized difference vegetation index (NDVI). The results suggest that, in contrast to using all bands for wildfire detection, selecting specific band combinations yields superior performance. Additionally, our study underscores the positive impact of integrating Sentinel-5 aerosol data for wildfire detection. The code and dataset are available online (https://zenodo.org/records/10881058).