Backscatter communication (BC) has emerged as a key technology to satisfy the increasing need for low-cost and green Internet-of-Things (IoT) connectivity, especially in large-scale deployments. Unlike the monostatic BC (MoBC), the bistatic BC (BiBC) has the possibility to decrease the round-trip path loss by having the carrier emitter (CE) and the reader in different locations. Therefore, this work investigates the BiBC in the context of cell-free multiple-input multiple-output (MIMO) networks by exploring the optimal selection of CE and reader among all access points, leveraging prior knowledge about the area where the backscatter device (BD) is located. First, a maximum a posteriori probability (MAP) detector to decode the BD information bits is derived. Then, the exact probability of error for this detector is obtained. In addition, an algorithm to select the best CE-reader pair for serving the specified area is proposed. Finally, simulation results show that the error performance of the BC is improved by the proposed algorithm compared to the benchmark scenario.